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Transition metal (TM) based catalysts have been considered promising candidates for SOR but suffer from limited activity due to the excessive bond strength from TM\u2010S<jats:sup>2\u2212<\/jats:sup> d\u2010p orbit coupling. Herein, we propose a feasible strategy of screening direct d\u2010p orbit hybridization between TM and S<jats:sup>2\u2212<\/jats:sup> by constructing the Turing structure composed of lamellar stacking carbon\u2010confined nickel nanosheets. The optimized p\u2010p orbit coupling between electron\u2010injected carbon and S<jats:sup>2\u2212<\/jats:sup> enables exceptional catalytic activity and stability for sulfion degradation and energy\u2010efficient yet value\u2010added H<jats:sub>2<\/jats:sub> production. Specifically, it achieves a current density of 500\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> at an ultralow potential of 0.67\u2005V vs. RHE for alkaline SOR. Theoretical calculations indicate that the electron transfer from Ni imparts metallicity and a higher p\u2010band center to carbon shells, thereby contributing to optimized p\u2010p orbit hybridization and a thermodynamically favorable stepwise sulfion degradation. Practically, a two\u2010electrode flow cell achieves an industrial current density of 1\u2005A\u2009cm<jats:sup>\u22122<\/jats:sup> at an unprecedented low voltage of 0.91\u2005V while maintaining stability for over 300\u2005hours, and exhibits high productivities of 3.83 and 0.32\u2005kg h<jats:sup>\u22121<\/jats:sup> m<jats:sup>\u22122<\/jats:sup> for sulfur and H<jats:sub>2<\/jats:sub>, respectively.<\/jats:p>","DOI":"10.1002\/anie.202419572","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T10:58:50Z","timestamp":1732100330000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Screened d\u2010p Orbital Hybridization in Turing Structure of Confined Nickel for Sulfion Oxidation Accelerated Hydrogen Production"],"prefix":"10.1002","volume":"64","author":[{"given":"Yin","family":"Zhu","sequence":"first","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale CAS Key Laboratory of Materials for Energy Conversion Department of Materials Science and Engineering University of Science and Technology of China  Hefei Anhui 230026 P. 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