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Using oxidative dehydrogenation of hydrogen sulfide (H<jats:sub>2<\/jats:sub>S\u2010ODH) as a probe, we develop various metal single atoms on nitrogen\u2010doped carbon (M\u2010NDC) catalysts for controlling <jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010H<jats:sub>2<\/jats:sub>S, <jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010O<jats:sub>2<\/jats:sub> and investigating the difference in activity and selectivity. Combining theoretical and experimental results, a Sabatier relationship between the catalytic performance and <jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010O<jats:sub>2<\/jats:sub>\/<jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010H<jats:sub>2<\/jats:sub>S emerges. Mn\u2010NDC as the optimal catalyst shows excellent H<jats:sub>2<\/jats:sub>S conversion (&gt;90\u2009%) and sulfur selectivity (&gt;90\u2009%) in a wide range of O<jats:sub>2<\/jats:sub> concentrations over 100\u2005h. Such a high\u2010efficiency performance is attributed to appropriate <jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010H<jats:sub>2<\/jats:sub>S and <jats:italic>E<\/jats:italic><jats:sub>ads<\/jats:sub>\u2010O<jats:sub>2<\/jats:sub> on Mn\u2010N<jats:sub>4<\/jats:sub> sites, boosting redox cycle between Mn<jats:sup>2+<\/jats:sup> and Mn<jats:sup>3+<\/jats:sup>, as well as preferential formation of sulfur. This work provides a fundamental guidance for designing Sabatier optimal catalysts in L\u2212H models.<\/jats:p>","DOI":"10.1002\/anie.202419630","type":"journal-article","created":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T03:29:08Z","timestamp":1733369348000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Sabatier Optimal of Mn\u2010N<sub>4<\/sub> Single Atom Catalysts for Selective Oxidative Desulfurization"],"prefix":"10.1002","volume":"64","author":[{"given":"Hanfeng","family":"Ye","sequence":"first","affiliation":[{"name":"State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou Fujian 350108 P. R. 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