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However, finding an additive that can significantly enhance the durability of Zn anodes by inhibiting Zn dendrites and side reactions remains a considerable challenge. Herein, pyridine N\u2010oxide (PNO), a non\u2010substituted aromatic compound with a nitrogen positive charge\u2010induced N\u2192O bond, is explored as ZS additives for highly durable Zn plating\/stripping electrolytes (i.e., PNO\/ZS). The optimized PNO\n                    <jats:sub>0.03<\/jats:sub>\n                    \/ZS mixture demonstrates exceptional stability for Zn anodes, achieving a cycle life exceeding 4200\u2005h and a Coulombic efficiency of 99.9\u2009% at 1\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1\u2005mAh\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . It maintains over 1000\u2005h of life and a cumulative capacity of 2.5\u2005Ah\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , even when subjected to plating\/stripping conditions intensified by a factor of 5. Importantly, it enables Zn||\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    cells to sustain high\u2010current charge\/discharge cycles for over 5000 cycles, retaining 80\u2009% (125\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) of the initial capacity, which is the best performance reported for similar additive systems. This exceptional stability is ascribed to the highly reversible Zn anode plating\/stripping, facilitated by the suitable coordination interactions between the N\u2192O acceptor of PNO and the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    \/H\n                    <jats:sub>2<\/jats:sub>\n                    O donor, effectively inhibiting side reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420183","type":"journal-article","created":{"date-parts":[[2025,1,30]],"date-time":"2025-01-30T22:20:27Z","timestamp":1738275627000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Non\u2010Substituted Aromatic Pyridine N\u2010Oxide Additives with an Intrinsic N\u2192O Acceptor for Ultra\u2010Long\u2010Life Zn||MnO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Qin","family":"Kang","sequence":"first","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8476-1314","authenticated-orcid":false,"given":"Hongyu","family":"Liang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaomin","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuxu","family":"Xing","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures School of Mechanical Engineering Guangxi University  Nanning 530004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingzheng","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures School of Mechanical Engineering Guangxi University  Nanning 530004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuman","family":"Li","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shihao","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengda","family":"Tang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Pan","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Mesoscopic Chemistry of MOE School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tangming","family":"Mo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures School of Mechanical Engineering Guangxi University  Nanning 530004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongfeng","family":"Bu","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,9]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302302"},{"key":"e_1_2_8_2_1","author":"Chen J.","year":"2024","journal-title":"Angew. 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