{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T05:27:08Z","timestamp":1791523628415,"version":"4.3.4"},"reference-count":46,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2024,12,11]],"date-time":"2024-12-11T00:00:00Z","timestamp":1733875200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20145, 52072151, 52171211, 52102253, 52271218"],"award-info":[{"award-number":["U22A20145, 52072151, 52171211, 52102253, 52271218"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,2,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The rising of MXenes not only enriches the two\u2010dimensional material family but also brings more opportunities for diverse functional applications. However, the controllable synthesis of MXenes is still unsatisfied via the common liquid\u2010solid etching route, considering the unsolved problems like safety risk, time cost and easy oxidation. Herein, a facile yet efficient gas\u2010solid (G\u2010S) reaction methodology is devised by using hydrogen fluoride gas derived from fluorinated organics as the MAX etchant toward high\u2010efficiency fabrication of multiple MXenes and their derivatives. The innovative G\u2010S reaction strategy exhibits superb versatility to achieve different gram\u2010level MXenes (V<jats:sub>2<\/jats:sub>C, Ti<jats:sub>3<\/jats:sub>C<jats:sub>2<\/jats:sub>, Nb<jats:sub>2<\/jats:sub>C, Ti<jats:sub>2<\/jats:sub>N, Ti<jats:sub>3<\/jats:sub>CN, (Mo<jats:sub>2\/3<\/jats:sub>Y<jats:sub>1\/3<\/jats:sub>)<jats:sub>2<\/jats:sub>C) in a very short time, and even realizes in situ heteroatom doping or synchronous phase conversion of MXenes directly from MAX phases. The obtained MXenes and their derivatives exhibit excellent structure stability and high electron\/ion conductivity, making them promising materials for electrochemical applications. In particular, the N\u2010doped V<jats:sub>2<\/jats:sub>C MXene shows superior adsorption and catalytic activity toward lithium polysulfides for advanced lithium sulfur batteries.<\/jats:p>","DOI":"10.1002\/anie.202420287","type":"journal-article","created":{"date-parts":[[2024,11,26]],"date-time":"2024-11-26T22:45:03Z","timestamp":1732661103000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["General and Fast Gas\u2013Solid Synthesis of Functional MXenes and Derivatives on the Scale of Tens of Grams"],"prefix":"10.1002","volume":"64","author":[{"given":"Yang","family":"Liu","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sen","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoqiang","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maoqiang","family":"Shen","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyue","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhao","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuesen","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linrui","family":"Hou","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6484-8970","authenticated-orcid":false,"given":"Changzhou","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering University of Jinan  250022 Jinan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,11]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abf1581"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201102306"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature13970"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02578"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201809662"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6NR02253G"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-0657-0"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aba8311"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301349"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.add5901"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01201"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201800887"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015627"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305200"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403508"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201002094"},{"key":"e_1_2_8_17_1","author":"Liu Y.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702485"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103328"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302107"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202201559"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1904-x"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2013.01.008"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c02194"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00104-6"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT01247C"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0641704jes"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b06866"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11446"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2009.10.015"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/jrs.3036"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0RA00842G"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1583\/ab6706"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.97.115439"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2019.06.013"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2020.12.044"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201808107"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913343"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c09639"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201901942"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315178"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2020.104555"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202407042"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06326-8"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200894"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn1818"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202420287","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,8,4]],"date-time":"2025-08-04T13:47:04Z","timestamp":1754315224000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202420287"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,11]]},"references-count":46,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2025,2,17]]}},"alternative-id":["10.1002\/anie.202420287"],"URL":"https:\/\/doi.org\/10.1002\/anie.202420287","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,11]]},"assertion":[{"value":"2024-10-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-12-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202420287"}}