{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T03:36:42Z","timestamp":1791862602391,"version":"4.3.4"},"reference-count":55,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T00:00:00Z","timestamp":1736726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20212ACB203010"],"award-info":[{"award-number":["20212ACB203010"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20242BAB20412"],"award-info":[{"award-number":["20242BAB20412"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,2,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Introduction of a guest component into the active layer is a simple yet effective approach to enhance the performance of organic solar cells (OSCs). Despite various guest components successfully employed in the OSCs, efficient guest components require deliberate design and ingenious inspiration, which still remains a big challenge for developing high performance OSCs. In this work, we propose a concept of \u201cstructural gene\u201d engineering to create a new \u201cdouble\u2010gene\u201d small molecule (L\u2010DBDD) by simply combining the structures of both donor PM6 and acceptor L8\u2010BO. L\u2010DBDD inherit the features of both donor and acceptor, which naturally acts as a bridge between donor\/acceptor (D\/A) interfaces to strengthen D\/A interactions and compatibility. Incorporation of this \u201cdouble\u2010gene\u201d small molecule into the active layer can facilitate rapid charge dissociation and simultaneously optimize molecular packing for efficient charge transport. Consequently, the ternary OSC based on PM6\u2009:\u2009L\u2010DBDD\u2009:\u2009L8\u2010BO blend achieves a top power conversion efficiency (PCE) of 19.51\u2009%, significantly suppressing the binary control device (PCE=18.52\u2009%). These results demonstrate that the design concept of \u201cdouble\u2010gene\u201d small molecule by combination of the \u201cstructural gene\u201d of donor and acceptor provides a simple and meaningful guideline for guest component\u2010assisted highly efficient OSCs.<\/jats:p>","DOI":"10.1002\/anie.202420385","type":"journal-article","created":{"date-parts":[[2025,1,2]],"date-time":"2025-01-02T23:11:03Z","timestamp":1735859463000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["\u201cDouble\u2010Gene\u201d Small Molecule as Guest Component Promotes the Efficiency of Organic Solar Cells Beyond 19.5\u2009%"],"prefix":"10.1002","volume":"64","author":[{"given":"Jiawei","family":"Deng","sequence":"first","affiliation":[{"name":"Institute of Geriatrics Jiangxi Provincial People's Hospital The First Affiliated Hospital of Nanchang Medical College  Nanchang 330006 Jiangxi PR China"},{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiabin","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengkai","family":"Jin","sequence":"additional","affiliation":[{"name":"School of Physics Southeast University  Nanjing 211189 Jiangsu PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaorong","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute of Geriatrics Jiangxi Provincial People's Hospital The First Affiliated Hospital of Nanchang Medical College  Nanchang 330006 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shijing","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Qin","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaping","family":"Xie","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Anyang Normal University  Anyang 455002 Henan PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5288-5563","authenticated-orcid":false,"given":"Lie","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiwang","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/ Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang 330031 Jiangxi PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,13]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01244-y"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16621-x"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29803-6"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202177"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404297"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202208008"},{"key":"e_1_2_7_8_2","author":"Zeng R.","year":"2024","journal-title":"Nat. Energy"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.136515"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2023.109023"},{"key":"e_1_2_7_11_1","unstructured":"\u00a0"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-51359-w"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01557-z"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400342"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202308151"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE03989J"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202102420"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316295"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.04.007"},{"key":"e_1_2_7_21_1","unstructured":"\u00a0"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02977K"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202100830"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00630A"},{"key":"e_1_2_7_25_1","unstructured":"\u00a0"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007177"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01503"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003506"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107476"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008134"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr3001109"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202101733"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.06.020"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200329"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201100094"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201076"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9797(90)90067-X"},{"key":"e_1_2_7_39_1","unstructured":"\u00a0"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-022-1300-1"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-022-1517-2"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.04.002"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202111855"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006081"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313105"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000235"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103357"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008494"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.1c00306"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01327D"},{"key":"e_1_2_7_52_1","unstructured":"\u00a0"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02858H"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.150414"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202308159"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202420385","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,8,4]],"date-time":"2025-08-04T13:46:17Z","timestamp":1754315177000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202420385"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,13]]},"references-count":55,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2025,2,17]]}},"alternative-id":["10.1002\/anie.202420385"],"URL":"https:\/\/doi.org\/10.1002\/anie.202420385","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,13]]},"assertion":[{"value":"2024-10-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202420385"}}