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Different from the through\u2010bond conjugation mechanism in \u03c0\u2010conjugated luminophores, through\u2010space conjugation (TSC) plays dominant roles in CLgens. However, precisely controlling TSC to customize the optical properties of CLgens remains a significant challenge. This work proposes a novel strategy of high pressure to engineer TSC within tetraphenylalkanes (TPAs)\u2010based CLgens at molecular level. High\u2010pressure exploration enables accurate manipulation of clusteroluminescence and elucidates the intrinsic structure\u2013property relationships involved. Upon initial compression, the predominant molecular distortions marked by increased interfacial angles between benzene rings diminish TSC, resulting in anomalous hypochromatic shift in emission. Subsequently, considerable structural contraction enhances TSC and suppresses molecular motion, resulting in a pronouncedly enhanced and bathochromic\u2010shifted emission. Notably, a series of TPAs\u2010based CLgens exhibit intense white\u2010light emission upon pressure release, attributed to irreversible structural distortion and destruction. This study not only advances the understanding of CLgens, but also underscores the crucial structural factors for effective TSC control, paving the way for establishing new photophysical theories for aggregate science.<\/jats:p>","DOI":"10.1002\/anie.202420502","type":"journal-article","created":{"date-parts":[[2024,11,25]],"date-time":"2024-11-25T22:20:39Z","timestamp":1732573239000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Pressure\u2010Engineered Through\u2010Space Conjugation for Precise Control of Clusteroluminescence"],"prefix":"10.1002","volume":"64","author":[{"given":"Yayun","family":"Wang","sequence":"first","affiliation":[{"name":"School of Physics Science and Information Technology Liaocheng University  Liaocheng Shandong 252000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zuping","family":"Xiong","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of 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