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The difficulty of using CO\n                    <jats:sub>2<\/jats:sub>\n                    as an important resource for the chemical industry lies in the high stability of the molecule and its associated inertia. In this work, we demonstrate how to overcome these limitations by utilizing a solid oxide electrolysis cell (SOEC) with an optimized cathode to produce dry CO through the high\u2010temperature electrolysis of CO\n                    <jats:sub>2<\/jats:sub>\n                    . We further integrate this process with a synthesis setup in a continuous\u2010flow coil reactor to boost reactivity in various carbonylation processes, including in amino\u2010, alkoxy\u2010, and phenoxycarbonylation, carbonylative Sonogashira couplings, or the synthesis of redox\u2010active esters. Ultimately, our approach offers a platform strategy for the rapid, scalable, and continuous production of carbonyl compounds directly from CO\n                    <jats:sub>2<\/jats:sub>\n                    while eliminating the requirement for storing large CO quantities.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420578","type":"journal-article","created":{"date-parts":[[2025,4,7]],"date-time":"2025-04-07T03:22:32Z","timestamp":1743996152000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Online Coupling High\u2010Temperature Electrolysis with Carbonylation Reactions: A Powerful Method for Continuous Carbon Dioxide Utilization"],"prefix":"10.1002","volume":"64","author":[{"given":"Kristof","family":"Stagel","sequence":"first","affiliation":[{"name":"Institute of Applied Synthetic Chemistry TU Wien  Getreidemarkt 9\/163 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kirsten","family":"Rath","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics TU Wien  Getreidemarkt 9\/164 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Prasad M.","family":"Kathe","sequence":"additional","affiliation":[{"name":"Institute of Applied Synthetic Chemistry TU Wien  Getreidemarkt 9\/163 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Schn\u00fcrch","sequence":"additional","affiliation":[{"name":"Institute of Applied Synthetic Chemistry TU Wien  Getreidemarkt 9\/163 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tobias M.","family":"Huber","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics TU Wien  Getreidemarkt 9\/164 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander K.","family":"Opitz","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics TU Wien  Getreidemarkt 9\/164 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katharina","family":"Bica\u2010Schr\u00f6der","sequence":"additional","affiliation":[{"name":"Institute of Applied Synthetic Chemistry TU Wien  Getreidemarkt 9\/163 Wien 1060 Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,7]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.18970300288"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19260590442"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.2174\/1385272023373699"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja039464y"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900013"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar400222k"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500035q"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1213\/ANE.0000000000001461"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.4103\/neuroindia.NI_990_16"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/je00011a029"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/je950274f"},{"key":"e_1_2_8_12_1","first-page":"38","author":"Henni A.","year":"1999","journal-title":"J. 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