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Remarkably, no single ternary beryllium nitride with a transition metal is known. Here, we report on the synthesis and properties of the first transition metal nitridoberyllates, namely W\n                    <jats:sub>2<\/jats:sub>\n                    Be\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    and W\n                    <jats:sub>4<\/jats:sub>\n                    Be\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>9<\/jats:sub>\n                    . Both compounds were synthesized in a high\u2010temperature high\u2010pressure approach from Be\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    and W, using azide generated N\n                    <jats:sub>2<\/jats:sub>\n                    as an oxidizing agent. The crystal structures, consisting of alternating layers of WN\n                    <jats:sub>6<\/jats:sub>\n                    trigonal prisms and BeN\n                    <jats:sub>4<\/jats:sub>\n                    tetrahedra, were elucidated by single\u2010crystal X\u2010ray diffraction (sc\u2010XRD). The separating nitridoberyllate layers show either ambient temperature (\u03b1\u2010Be\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    type) or high temperature (\u03b2\u2010Be\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    type) motifs. W\n                    <jats:sub>2<\/jats:sub>\n                    Be\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    was further corroborated by infrared (IR), nuclear magnetic resonance (NMR) and UV\/Vis spectroscopy and vibrating sample magnetometry (VSM) measurements. The latter revealed a mixed valence with an intermediate oxidation state of 3.5 for the W atoms. Both, the synthesis of the first transition metal nitridoberyllates and the synthesis approach using elemental W pave the way to a new field of nitride chemistry.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420583","type":"journal-article","created":{"date-parts":[[2024,11,8]],"date-time":"2024-11-08T03:21:23Z","timestamp":1731036083000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Combination of Ambient and High\u2010Temperature Beryllium Nitride Motifs in W\n                    <sub>2<\/sub>\n                    Be\n                    <sub>4<\/sub>\n                    N\n                    <sub>5<\/sub>\n                    and W\n                    <sub>4<\/sub>\n                    Be\n                    <sub>8<\/sub>\n                    N\n                    <sub>9<\/sub>"],"prefix":"10.1002","volume":"64","author":[{"given":"Georg","family":"Krach","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dominik","family":"Werhahn","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kristian","family":"Witthaut","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5630-7691","authenticated-orcid":false,"given":"Dirk","family":"Johrendt","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-8035","authenticated-orcid":false,"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,26]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X58000323"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X5700225X"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0304-8853(80)90845-8"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X61000152"},{"key":"e_1_2_3_5_1","first-page":"121","volume":"6","author":"Verkhoro L. 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