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However, most current CTO catalysts require a high\u2010temperature condition of 300\u2013450\u2009\u00b0C, resulting in high energy consumption and possible aggregation among active sites. Herein, we developed an efficient iron\u2010based catalyst modified with high\u2010sodium content (7\u2009%) and low\u2010cobalt content (2\u2009%), achieving a CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion of 22.0\u2009% and an olefin selectivity of 55.9\u2009% at 240\u2009\u00b0C and 1000\u2005mL\/g\/h, and it is even active at 180\u2009\u00b0C and 4000\u2005mL\/g\/h with more than 25\u2009% olefins in hydrocarbons. The catalyst was kept stable under continuous operating conditions of 500\u2005hours. Numerous characterizations and calculations reveal high content of sodium as an electronic promoter enhances the stability of the active anorthic Fe\n                    <jats:sub>5<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    phase at low temperatures. Further incorporating the above catalyst with cobalt, as a structural promoter, causes Fe species to form a Fe\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Co\n                    <jats:sub>\n                      <jats:italic>y<\/jats:italic>\n                    <\/jats:sub>\n                    alloying phase, which in turn facilitates the formation of higher active anorthic (Fe\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Co\n                    <jats:sub>\n                      <jats:italic>y<\/jats:italic>\n                    <\/jats:sub>\n                    )\n                    <jats:sub>5<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    phase, different from the conventional carbides and alloy carbides. An in\u2010depth investigation of the synergistic effects of structural and electronic promoters can improve catalyst performance, increase reaction efficiency and cost\u2010effectiveness, and provide profound insights for understanding and optimizing CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420621","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T01:29:42Z","timestamp":1732066182000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Low\u2010temperature CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Olefins on Anorthic NaCoFe Alloy Carbides"],"prefix":"10.1002","volume":"64","author":[{"given":"Jianxiang","family":"Han","sequence":"first","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"},{"name":"School of Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Han","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"},{"name":"School of Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiafeng","family":"Yu","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yannan","family":"Sun","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"},{"name":"School of Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiwen","family":"Cui","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"},{"name":"School of Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingjie","family":"Ge","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4191-578X","authenticated-orcid":false,"given":"Jian","family":"Sun","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,27]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13638-9"},{"key":"e_1_2_7_2_1","unstructured":"\u00a0"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00502H"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b03251"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603556"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009620"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-022-01154-9"},{"key":"e_1_2_7_8_1","unstructured":"\u00a0"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00260K"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-47270-z"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119648"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC04409B"},{"key":"e_1_2_7_13_1","unstructured":"\u00a0"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15174"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0144-z"},{"key":"e_1_2_7_16_2","author":"Guo L.","year":"2022","journal-title":"Chem. 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