{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T12:17:16Z","timestamp":1788351436676,"version":"build-2803163510"},"reference-count":44,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T00:00:00Z","timestamp":1733356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T00:00:00Z","timestamp":1733356800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,3,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    CO\n                    <jats:sub>2<\/jats:sub>\n                    capture technology can mitigate greenhouse gas emissions and global warming. CO\n                    <jats:sub>2<\/jats:sub>\n                    capture driven by electrochemical reactions is attractive because the operation is carried out at normal temperature and pressure and involves a simple input system using electrical energy. Although promising metal complexes with high CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation performance have been reported, there are few studies on systems that combine electrochemical reactions and metal complexes. Here, we demonstrated stable CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation\u2010release cycles using an electrochemical system with trinuclear Zn(II) complex (Zn\n                    <jats:sub>3<\/jats:sub>\n                    <jats:bold>L<\/jats:bold>\n                    ) as the CO\n                    <jats:sub>2<\/jats:sub>\n                    fixative and an ionic liquid as a supporting electrolyte for the stable operation. This system showed a faster CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation rate than that of an aqueous alkaline solution at the same concentration. Continuous release and refixation of CO\n                    <jats:sub>2<\/jats:sub>\n                    were achieved by decomposition and reconstruction of the complex structure induced by H\n                    <jats:sup>+<\/jats:sup>\n                    and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    supplied from a bipolar membrane equipped in the electrolytic cell. The CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation\u2010release cycle was demonstrated even for dilute CO\n                    <jats:sub>2<\/jats:sub>\n                    (450\u2005ppm) in air, where the CO\n                    <jats:sub>2<\/jats:sub>\n                    capture rate reached approximately 46\u2009% of CO\n                    <jats:sub>2<\/jats:sub>\n                    contained in the air under an air flow condition of 200\u2005mL\u2009\u22c5\u2009min\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This case, combining electrochemical drive and metal complexes, will provide a new option for CO\n                    <jats:sub>2<\/jats:sub>\n                    capture technology.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420703","type":"journal-article","created":{"date-parts":[[2024,11,29]],"date-time":"2024-11-29T01:00:13Z","timestamp":1732842013000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electrochemical CO\n                    <sub>2<\/sub>\n                    Fixation and Release Cycle Featuring a Trinuclear Zinc Complex for Direct Air Capture"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1512-9080","authenticated-orcid":false,"given":"Masakazu","family":"Murase","sequence":"first","affiliation":[{"name":"Toyota Central R&amp;D Labs., Inc.  41-1 Yokomichi, Nagakute Aichi 480-1192 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