{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T23:48:46Z","timestamp":1792021726397,"version":"4.4.0"},"reference-count":65,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2025,1,9]],"date-time":"2025-01-09T00:00:00Z","timestamp":1736380800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,1,9]],"date-time":"2025-01-09T00:00:00Z","timestamp":1736380800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB2502000"],"award-info":[{"award-number":["2022YFB2502000"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U21A20332"],"award-info":[{"award-number":["U21A20332"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52301266"],"award-info":[{"award-number":["52301266"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,2,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    As traditional lithium\u2010ion batteries near their theoretical limits, the advancement of lithium\u2010metal batteries (LMBs) becomes crucial for achieving higher energy densities. However, uncontrolled ion transport and unstable solid electrolyte interface (SEI) layer are key factors inducing lithium dendrite growth, hindering the development of LMBs. Separator modification is an effective strategy to address the challenges of LMBs. To tackle the issues, a donor\u2013acceptor polymer (ArMT) consisting of benzene rings and triazine was successfully synthesized and modified onto commercial polypropylene (ArMT@PP) as separators for LMBs. Benefitting from the highly lithiophilic triazine organic units, this ArMT exhibits affinity towards Li\n                    <jats:sup>+<\/jats:sup>\n                    and simplifies the solvation structure of Li\n                    <jats:sup>+<\/jats:sup>\n                    during the diffusion process, thus decreasing the ion diffusion activation energy, thereby accelerating the migration of Li\n                    <jats:sup>+<\/jats:sup>\n                    . Furthermore, triazine organic units with appropriate pore size regulate the plating\/stripping behavior of lithium metal anodes, thereby facilitating the formation of a stable solid electrolyte interface (SEI) layer. As a result, the assembled Li|ArMT@PP|Li symmetric cells exhibit stable plating\/stripping over 800\u2005h. Moreover, the LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    |ArMT@PP|Li cells achieved excellent cycling stability with 127.3\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 1200 cycles at 1\u2005C and a high capacity retention of 90.58\u2009%. This design strategy ensures a durable and dendrite\u2010free anode and paves the way for the development of high\u2010energy\u2010density LMBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202420973","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T11:03:33Z","timestamp":1734951813000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["A Lithiophilic Donor\u2013Acceptor Polymer Modified Separator for High\u2010Performance Lithium Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Tao","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xijun","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suping","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Yang","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangkun","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weizhen","family":"Fan","sequence":"additional","affiliation":[{"name":"Research and Development Center Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou 510765 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxue","family":"Wu","sequence":"additional","affiliation":[{"name":"Analytical&amp;Testing Center Guangdong University of Technology  Guangzhou 510006 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingwei","family":"Zhao","sequence":"additional","affiliation":[{"name":"Research and Development Center Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou 510765 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7078-8046","authenticated-orcid":false,"given":"Jun","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanping","family":"Huo","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 PR China"},{"name":"Analytical&amp;Testing Center Guangdong University of Technology  Guangzhou 510006 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2020.02.003"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-34464-6"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203744"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202103503"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003752"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.06.015"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c03643"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4783-7"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007434"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2017.16"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01435D"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.10.017"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.08.056"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.102957"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c00801"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202100537"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300725"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.10.019"},{"key":"e_1_2_7_19_1","author":"Tian Jinya.","year":"2023","journal-title":"Adv. Mater."},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202204035"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE01674J"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00664F"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c02719"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202202651"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300023"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00115J"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611946"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.74"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317393"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10008-021-04955-5"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-024-01509-y"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02803H"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.01.016"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212466"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208438"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201907702"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200304940"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC02231J"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202204007"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202401146"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202400626"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201808392"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2011.02.025"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105178"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200337"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202200919"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104124"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab1595"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1712895115"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12032"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202109377"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202206"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.12.046"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202101827"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301586"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202200383"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10073K"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202100793"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.04.016"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c00819"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202112711"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-022-00190-3"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.138536"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c01243"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003092"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202420973","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202420973","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202420973","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T15:08:40Z","timestamp":1790780920000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202420973"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,9]]},"references-count":65,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2025,2,24]]}},"alternative-id":["10.1002\/anie.202420973"],"URL":"https:\/\/doi.org\/10.1002\/anie.202420973","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,9]]},"assertion":[{"value":"2024-10-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202420973"}}