{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T04:03:20Z","timestamp":1793246600207,"version":"4.5.0"},"reference-count":63,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:00:00Z","timestamp":1736899200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:00:00Z","timestamp":1736899200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB2404400"],"award-info":[{"award-number":["2022YFB2404400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92263206, U23A20577, 52372168 and 21975006"],"award-info":[{"award-number":["92263206, U23A20577, 52372168 and 21975006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["2222001 and KM202110005009"],"award-info":[{"award-number":["2222001 and KM202110005009"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,3,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Manganese\u2010based (Mn\u2010based) layered oxides have emerged as competitive cathode materials for sodium\u2010ion batteries (SIBs), primarily due to their high energy density, cost\u2010effectiveness, and potential for mass production. However, these materials often suffer from irreversible oxygen redox reactions, significant phase transitions, and microcrack formation, which lead to considerable internal stress and degradation of electrochemical performance. This study introduces a high\u2010entropy engineering strategy for P2\u2010type Mn\u2010based layered oxide cathodes (HE\u2010NMCO), wherein a multi\u2010ingredient cocktail effect strengthens the lattice framework by modulating the local environmental chemistry. This innovative approach fosters sustainable reversible oxygen activity, mitigates stress concentrations at grain boundaries, and accelerates Na\n                    <jats:sup>+<\/jats:sup>\n                    transport kinetics. The resulting robust lattice framework with optimized elemental interactions significantly improves structural integrity and reduces the formation of intragranular fractures. Consequently, HE\u2010NMCO demonstrates remarkable cycling stability, retaining 93.5\u2009% capacity after 100 deep (de)sodiation cycles, alongside an enhanced rate capability of 134.1\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5\u2005C. Notably, comparative studies through multimodal characterization techniques highlight HE\u2010NMCO\u2032s superior reversibility in oxygen anion redox (OAR) reactions over extensive cycling, contrasting sharply with conventional NMCO cathode. This work elucidates the potential for advancing high energy and power density Mn\u2010based cathodes for SIBs through local species diversity.\n                  <\/jats:p>","DOI":"10.1002\/anie.202421089","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T11:03:40Z","timestamp":1734951820000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["A High\u2010Entropy Engineering on Sustainable Anionic Redox Mn\u2010Based Cathode with Retardant Stress for High\u2010Rate Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Shiqi","family":"Liu","sequence":"first","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"},{"name":"Institute of Matter Science Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangzheng","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zengqing","family":"Zhuo","sequence":"additional","affiliation":[{"name":"Advanced Light Source Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongdong","family":"Xiao","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences  Beijing 100190 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongyi","family":"Cui","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulong","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boya","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianhao","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuming","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lisi","family":"Liang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"},{"name":"College of Metallurgical Engineering Xi'an University of Architecture and Technology  Xi'an 710055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Houbing","family":"Huang","sequence":"additional","affiliation":[{"name":"Advanced Research Institute of Multidisciplinary Science Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanli","family":"Yang","sequence":"additional","affiliation":[{"name":"Advanced Light Source Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0204-9943","authenticated-orcid":false,"given":"Haijun","family":"Yu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"},{"name":"Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology  Beijing 100124 China"},{"name":"Institute of Matter Science Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00442E"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE01807F"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500192f"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00846B"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aar6018"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1854-3"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-00870-8"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.201800205"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2016.06.005"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202106171"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE02313B"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310659"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC47351A"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301568"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7EE02995K"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE00465E"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100159"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202404459"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abc5454"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.08.003"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adem.200300567"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-024-00654-5"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-019-0121-4"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9485"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201912171"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00879"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02353"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2023.10.016"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1088\/2752-5724\/ac8ab9"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2023.101446"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2024.100245"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105404"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008194"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301314"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206625"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-18423-7"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200702"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404549"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.10.022"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3309"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407720"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01890"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01209-1"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-22523-3"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aaw3871"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.etran.2021.100118"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c00913"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300714"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115552"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE02991A"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-25074-9"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30942-z"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05498"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05111"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12119"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.11.014"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300217"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-00816-0"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202208726"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ado4472"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05020G"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c16194"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.4c02235"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202421089","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202421089","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202421089","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T16:40:40Z","timestamp":1790181640000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202421089"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,15]]},"references-count":63,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,3,3]]}},"alternative-id":["10.1002\/anie.202421089"],"URL":"https:\/\/doi.org\/10.1002\/anie.202421089","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,15]]},"assertion":[{"value":"2024-10-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202421089"}}