{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T17:08:00Z","timestamp":1790183280850,"version":"4.1.0"},"reference-count":78,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100023675","name":"College of Design and Engineering, National University of Singapore","doi-asserted-by":"publisher","award":["A-0001423-06-00"],"award-info":[{"award-number":["A-0001423-06-00"]}],"id":[{"id":"10.13039\/501100023675","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001381","name":"National Research Foundation Singapore","doi-asserted-by":"publisher","award":["A-0009163-01-00"],"award-info":[{"award-number":["A-0009163-01-00"]}],"id":[{"id":"10.13039\/501100001381","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012600","name":"ShanghaiTech University","doi-asserted-by":"publisher","award":["EM02161943"],"award-info":[{"award-number":["EM02161943"]}],"id":[{"id":"10.13039\/501100012600","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,3,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Boron dipyrromethene (BODIPY)\u2010based zirconium metal\u2013organic frameworks (Zr\u2010MOFs) possess strong light\u2010harvesting capabilities and great potential for artificial photosynthesis without the use of sacrificial reagents. However, their direct preparation has not yet been achieved due to challenges in synthesizing suitable ligands. Herein, we reported the first successful direct synthesis of BODIPY\u2010based Zr\u2010MOFs, utilizing CO\n                    <jats:sub>2<\/jats:sub>\n                    as a feedstock. By controlling synthetic conditions, we successfully obtained two distinct Zr\u2010MOFs. The first, CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Zr\n                    <jats:sub>6<\/jats:sub>\n                    \u2010DEPB, exhibits a face\u2010centered cubic (\n                    <jats:bold>fcu<\/jats:bold>\n                    ) topology based on a Zr\n                    <jats:sub>6<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    \u2010O)\n                    <jats:sub>4<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    \u2010OH)\n                    <jats:sub>4<\/jats:sub>\n                    node, while the second, CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Zr\n                    <jats:sub>12<\/jats:sub>\n                    \u2010DEPB, features a hexagonal closed packed (\n                    <jats:bold>hcp<\/jats:bold>\n                    ) topology, structured around a Zr\n                    <jats:sub>12<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    \u2010O)\n                    <jats:sub>8<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    \u2010OH)\n                    <jats:sub>8<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>2<\/jats:sub>\n                    \u2010OH)\n                    <jats:sub>6<\/jats:sub>\n                    node. Both MOFs demonstrated excellent crystallinity, as verified through powder X\u2010ray diffraction and high\u2010resolution transmission electron microscopy analyses. These MOF catalysts displayed suitable photocatalytic redox potentials for the reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO using H\n                    <jats:sub>2<\/jats:sub>\n                    O as the electron donor in the absence of co\u2010catalyst or toxic sacrificial reagent. Under light irradiation, CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Zr\n                    <jats:sub>12<\/jats:sub>\n                    \u2010DEPB and CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Zr\n                    <jats:sub>6<\/jats:sub>\n                    \u2010DEPB offered high CO yields of 16.72 and 13.91\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively, with nearly 100\u2009% selectivity. CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake and photoelectrochemical experiments revealed key insights into the mechanisms driving the different catalytic activities of the two MOFs. These BODIPY and CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based, light\u2010responsive Zr\u2010MOFs represent a promising platform for the development of efficient photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202421248","type":"journal-article","created":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T11:34:49Z","timestamp":1735731289000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Direct Synthesis of Topology\u2010Controlled BODIPY and CO\n                    <sub>2<\/sub>\n                    \u2010Based Zirconium Metal\u2010Organic Frameworks for Efficient Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"64","author":[{"given":"Bo","family":"Song","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wentao","family":"Song","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhang","family":"Liang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of High-Resolution Electron Microscopy &amp; School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry State Key Laboratory of Marine Pollution City University of Hong Kong  Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bowen","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"He","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Hong Kong University of Science and Technology  Clear Water Bay Kowloon Hong Kong 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhang","family":"Ma","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of High-Resolution Electron Microscopy &amp; School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruquan","family":"Ye","sequence":"additional","affiliation":[{"name":"Department of Chemistry State Key Laboratory of Marine Pollution City University of Hong Kong  Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben Zhong","family":"Tang","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Hong Kong University of Science and Technology  Clear Water Bay Kowloon Hong Kong 999077 China"},{"name":"Shenzhen Institute of Aggregate Science and Technology School of Science and Engineering The Chinese University of Hong Kong  Shenzhen Guangdong 518172 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Zhou","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of High-Resolution Electron Microscopy &amp; School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0956-2777","authenticated-orcid":false,"given":"Bin","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,10]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0033-5"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08688"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2021.100719"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0431-1"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00843B"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16742-3"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303785"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104442"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310600"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313648"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-023-00243-w"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwad275"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212355"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2738-2"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-00512-x"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01157-6"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-00992-7"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217565"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00256H"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215858"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00326"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00380"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11987"},{"key":"e_1_2_7_26_1","unstructured":"\u00a0"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214177"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201600647"},{"key":"e_1_2_7_29_1","unstructured":"\u00a0"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0308-5"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08773"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01920"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00665-3"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11027"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301728"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA00429F"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102729"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02425"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319177"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704388"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608597"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.023.202303055"},{"key":"e_1_2_7_43_1","unstructured":"\u00a0"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05659-7"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004563"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c03136"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904537"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05530"},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213783"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214698"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215074"},{"key":"e_1_2_7_53_1","unstructured":"\u00a0"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic502219y"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11647"},{"key":"e_1_2_7_56_1","unstructured":"\u00a0"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja206029a"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA06989E"},{"key":"e_1_2_7_59_1","unstructured":"\u00a0"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12416"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906198y"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b05494"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.3390\/nano10101925"},{"key":"e_1_2_7_64_1","unstructured":"\u00a0"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03476"},{"key":"e_1_2_7_66_2","author":"Kadota K.","year":"2024","journal-title":"Acc. Chem. Res."},{"key":"e_1_2_7_67_1","unstructured":"\u00a0"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01640"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906890"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913284"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412553"},{"key":"e_1_2_7_72_1","unstructured":"\u00a0"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40117-z"},{"key":"e_1_2_7_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04185"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31474-2"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409925"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC01985G"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202421248","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202421248","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202421248","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T16:40:31Z","timestamp":1790181631000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202421248"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,10]]},"references-count":78,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,3,3]]}},"alternative-id":["10.1002\/anie.202421248"],"URL":"https:\/\/doi.org\/10.1002\/anie.202421248","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,10]]},"assertion":[{"value":"2024-11-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202421248"}}