{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T02:49:37Z","timestamp":1790390977875,"version":"4.1.0"},"reference-count":70,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:00:00Z","timestamp":1736899200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:00:00Z","timestamp":1736899200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,3,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic urea synthesis from carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) and nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) offers a promising alternative to traditional industrial methods. However, current catalysts face limitations in the supplies of CO* and N\n                    <jats:sub>related<\/jats:sub>\n                    * intermediates, and their coupling, resulting in unsatisfactory urea production efficiency and energy consumption. To overcome these challenges, we carried out tandem electrosynthesis approach using ruthenium dioxide\u2010supported palladium\u2010gold alloys (Pd\n                    <jats:sub>2<\/jats:sub>\n                    Au\n                    <jats:sub>1<\/jats:sub>\n                    \/RuO\n                    <jats:sub>2<\/jats:sub>\n                    ). This catalyst system effectively catalyzes CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010CO* conversion on Pd\n                    <jats:sub>2<\/jats:sub>\n                    Au\n                    <jats:sub>1<\/jats:sub>\n                    and NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010to\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    * conversion on RuO\n                    <jats:sub>2<\/jats:sub>\n                    . Crucially, the minimized work function difference between two components promotes remote CO* spillover from Pd\n                    <jats:sub>2<\/jats:sub>\n                    Au\n                    <jats:sub>1<\/jats:sub>\n                    to RuO\n                    <jats:sub>2<\/jats:sub>\n                    , improving effective coupling of CO* and NH\n                    <jats:sub>2<\/jats:sub>\n                    * for urea production. Our catalyst demonstrated exceptional performance, achieving a record\u2010high Faradaic efficiency for urea (FE\n                    <jats:sub>urea<\/jats:sub>\n                    ) of 75.6\u00b10.5\u2009% and a urea production rate (\n                    <jats:italic>r<\/jats:italic>\n                    <jats:sub>urea<\/jats:sub>\n                    ) of 73.5\u00b10.8\u2005mmol\u2009g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Notably, this was accomplished with an ultralow energy consumption of 18.9\u2005kWh\u2009kg\n                    <jats:sub>urea<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    . We also successfully demonstrate the long\u2010term stability of our catalyst in a flow cell, achieving over 160\u2005h of uninterrupted urea and formate production with consistent profitability. This achievement represents a significant step towards the large\u2010scale practical application of sustainable urea electrosynthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202421266","type":"journal-article","created":{"date-parts":[[2025,1,7]],"date-time":"2025-01-07T22:41:03Z","timestamp":1736289663000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Remote Carbon Monoxide Spillover Improves Tandem Urea Electrosynthesis"],"prefix":"10.1002","volume":"64","author":[{"given":"Jia\u2010Yuan","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Northwestern Polytechnical University  Youyi Road No. 127 Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue\u2010Fei","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Northwestern Polytechnical University  Youyi Road No. 127 Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin\u2010Sen","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Xi'an Jiaotong University  Xianning West Road No. 28, Xi An Shi Xi'an 710048 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Xi'an Jiaotong University  Xianning West Road No. 28, Xi An Shi Xi'an 710048 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Shaanxi Normal University  Xi'an 710062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2054-908X","authenticated-orcid":false,"given":"Bao Yu","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure Hubei Engineering Research Center for Biomaterials and Medical Protective Materials Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,15]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110158"},{"key":"e_1_2_7_2_1","unstructured":"\u00a0"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1476"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.10.010"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10714"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01020-4"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-022-00379-5"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-47765-9"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.12.025"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00561A"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04912"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402215"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210958"},{"key":"e_1_2_7_16_1","unstructured":"\u00a0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.345"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-021-00741-3"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00008G"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201500"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44131-z"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301957"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402684"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15438"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-019-0551-6"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02179"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806432"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202604"},{"key":"e_1_2_7_30_1","unstructured":"\u00a0"},{"key":"e_1_2_7_31_2","author":"Huang 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