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Traditional catalysts require high temperatures and pressures to facilitate CH\n                    <jats:sub>4<\/jats:sub>\n                    conversion, constrained by their rigid structures which lack the flexibility needed for optimizing complex reaction steps. This study introduces a novel Cu embedded liquid metal catalyst (Cu\u2010LMC) based on gallium alloys, characterized by dynamic, self\u2010adaptive structures that provide enhanced catalytic performance and selectivity. Our findings reveal that Cu\u2010LMC achieves a high methane conversion to methanol yield (5.9\u2005mol\u22c5g\n                    <jats:sub>Cu<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u22c5h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with a selectivity of 82\u2009%. The results show that mild surface oxidation significantly boosts the catalytic performance of Cu\u2010LMC by increasing active copper sites through the formation of a Cu\u2212O\u2212Ga configuration while preserving the catalyst\u2018s structural flexibility. In situ X\u2010ray Photoelectron Spectroscopy (XPS) and X\u2010ray Absorption Fine Structure (XAFS) analyses, along with ab initio Molecular Dynamics (AIMD) simulations, demonstrate that the Cu\u2010LMC enables self\u2010adaptive structural adjustments that lower methanol desorption energy and increase the energy barrier for by\u2010product formation, optimizing the overall methane conversion process. The results underscore the importance of designing catalysts with dynamic and adaptable structures to overcome traditional limitations and improve efficiency in catalytic reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202421554","type":"journal-article","created":{"date-parts":[[2025,2,4]],"date-time":"2025-02-04T09:20:02Z","timestamp":1738660802000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Improving the Methane Oxidation by Self\u2010Adaptive Optimization of Liquid\u2010Metal Catalysts"],"prefix":"10.1002","volume":"64","author":[{"given":"Haoran","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Endocrinology Institute of Endocrine and Metabolic Diseases The First Affiliated Hospital of USTC Division of Life Sciences and Medicine University of Science and Technology of China  Hefei 230001 China"},{"name":"Deep Space Exploration Laboratory\/School of Chemistry and 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