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More precisely, we describe the general reactivity of [(Cp*\u2010BR\n                    <jats:sub>2<\/jats:sub>\n                    )Fe(diphosphine)H], which contains an intramolecularly positioned Lewis acid, and its cooperative reactivity with CO\n                    <jats:sub>2<\/jats:sub>\n                    . Control experiments underscore the critical nature of borane incorporation for transforming CO\n                    <jats:sub>2<\/jats:sub>\n                    to reduced products, a reaction that does not occur for unfunctionalized [Cp*Fe(diphosphine)H]. Additional experiments highlight relevance of borane hybridization and substituent effects. Mechanistic studies performed in the presence and absence of CO\n                    <jats:sub>2<\/jats:sub>\n                    emphasize the significance of carbonyl substrate to catalyst longevity. Lessons from these reactions were also transferable \u2013 with such borane\u2010containing complexes enabling the chemoselective reduction of aldehydes in the presence of alkenes. These findings provide valuable insights into metal\u2010ligand cooperative design strategies for carbonyl reduction and illustrate the versatility of intramolecularly positioned Lewis acids for otherwise challenging chemical transformations.\n                  <\/jats:p>","DOI":"10.1002\/anie.202421599","type":"journal-article","created":{"date-parts":[[2025,1,7]],"date-time":"2025-01-07T12:48:25Z","timestamp":1736254105000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["CO\n                    <sub>2<\/sub>\n                    Reduction at a Borane\u2010Modified Iron Complex: A Secondary Coordination Sphere Strategy"],"prefix":"10.1002","volume":"64","author":[{"given":"Connor S.","family":"Durfy","sequence":"first","affiliation":[{"name":"Department of Chemistry Western University  1151 Richmond Street London ON N8K 3G6 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joseph A.","family":"Zurakowski","sequence":"additional","affiliation":[{"name":"Department of Chemistry Western University  1151 Richmond Street London ON N8K 3G6 Canada"},{"name":"Department of Chemistry and Biochemistry University of Windsor  401 Sunset Avenue Windsor ON N9B 3P4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2186-1040","authenticated-orcid":false,"given":"Marcus W.","family":"Drover","sequence":"additional","affiliation":[{"name":"Department of Chemistry Western University  1151 Richmond Street London ON N8K 3G6 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,16]]},"reference":[{"key":"e_1_2_8_1_1","volume-title":"Executive Summary. 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