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By regulating the hydrogen\u2010localization transfer effect in these 3D COFs, the Cz\u2212Co\u2212COF\u2212H containing cobalt glyoximate active centers exhibited excellent C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    performance, with an average C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    yield of 1755.33\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in pure C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    , also showed near 100\u2009% conversion of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    in 1\u2009% C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    contained crude C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    mixtures (industry\u2010relevant conditions), and finally obtain polymer grade C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    . In contrast, the Cz\u2212Co\u2212COF\u2212BF\n                    <jats:sub>2<\/jats:sub>\n                    only showed one fifth activity due to lack of hydrogen\u2010localization transfer. The density functional theory (DFT), projected density of states (PDOS) and molecular dynamics \u201cslow\u2010growth\u201d kinetic calculations based on precise 3D COF structures confirmed that the rapid hydrogen species transfer, enhanced water dissociation and suitable C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    adsorption in COFs jointly contributed efficient photocatalytic acetylene hydrogenation (PAH). This work provides new opportunity towards rational design and development of crystalline photocatalysts for C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202423091","type":"journal-article","created":{"date-parts":[[2025,1,8]],"date-time":"2025-01-08T10:18:50Z","timestamp":1736331530000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Hydrogen\u2010Localization Transfer Regulation in 3D COFs Enhances Photocatalytic Acetylene Semi\u2010Hydrogenation to Ethylene"],"prefix":"10.1002","volume":"64","author":[{"given":"Pei","family":"Huang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou 510006 P.R. 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