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This review covers recent developments in photocatalytic methodology for late\u2010stage transformations of complex carboxylic acids and their derivatives enabled by radical decarboxylation and deoxygenation, highlighting some representative and significant contributions in this field. These advancements are categorized based on the reactivity patterns exhibited by the carboxylic acids. Several activation modes to generate alkyl or aryl radical intermediates during decarboxylation of carboxylic acids are presented, namely, single\u2010electron transfer (SET) oxidation, ligand\u2010to\u2010metal charge transfer (LMCT), SET reduction, and energy transfer (EnT) processes. 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