{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T02:55:13Z","timestamp":1789181713916,"version":"build-2803163510"},"reference-count":59,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2025,4,24]],"date-time":"2025-04-24T00:00:00Z","timestamp":1745452800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52102261"],"award-info":[{"award-number":["52102261"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52103111"],"award-info":[{"award-number":["52103111"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Solid polymer electrolytes are promising candidates for solid\u2010state Li metal batteries owing to their favorable rheological properties and interfacial compatibility with cathodes and Li anodes. However, their limited ionic conductivity and low modulus lead to inferior electrochemical performance and dendrite growth. Herein, we developed a composite solid\u2010state electrolyte comprising vermiculite sheets and a poly(vinylidene fluoride) (PVDF) matrix with multivariate distribution and an anisotropic structure. Within this assembly, some vermiculite sheets were suspended in the PVDF matrix to facilitate Li salt dissociation and Li\n                    <jats:sup>+<\/jats:sup>\n                    transport, while others were tiled on the electrolyte surface, generating a dense, high\u2010modulus Li\n                    <jats:sub>2<\/jats:sub>\n                    SiO\n                    <jats:sub>3<\/jats:sub>\n                    \u2010rich solid electrolyte interphase via in situ electrochemical reduction, which further improved interfacial kinetics and suppressed dendrite growth. As a result, a high conductivity of 1.38\u00a0mS\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    was achieved at room temperature, and the Li||Li cells displayed robust stability over 3000\u00a0h. The LiNi\n                    <jats:sub>0.6<\/jats:sub>\n                    Co\n                    <jats:sub>0.2<\/jats:sub>\n                    Mn\n                    <jats:sub>0.2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ||Li full cells delivered a specific capacity of 172\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2\u00a0C and 86% capacity retention after 500 cycles at 0.5\u00a0C. Additionally, practical cycle performance at a high loading (4.4\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) was achieved in pouch cells. Overall, multivariate distribution and anisotropic structuring offers a novel perspective for the preparation of high\u2010performance solid\u2010state electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202423227","type":"journal-article","created":{"date-parts":[[2025,4,15]],"date-time":"2025-04-15T02:58:46Z","timestamp":1744685926000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Multivariate Distribution Structured Anisotropic Inorganic Polymer Composite Electrolyte for Long\u2010Cycle and High\u2010Energy All\u2010Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Ziqiang","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University  Hefei 230601 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University  Hefei 230601 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sen","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University  Hefei 230601 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiasheng","family":"Qian","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University  Hefei 230601 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiguo","family":"Hou","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University  Hefei 230601 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaona","family":"Li","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo 315200 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,24]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.103"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.01.028"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705702"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE03828K"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-019-0165-5"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00101"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.12.002"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.07.009"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06653-w"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abc8641"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002741"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(83)90083-8"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.08.002"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007598"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902029"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41808-3"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE03108J"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314273"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300243"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a006"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/35087538"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b02742"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/batt.202000081"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.06.040"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101537"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02663A"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202401428"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10864"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202101168"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00320-0"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201991"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.12.037"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06364"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-023-01341-2"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.10.055"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202110423"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202201718"},{"key":"e_1_2_7_38_1","author":"Feng G.","year":"2024","journal-title":"Angew. 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