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Here, we report a highly active bifunctional Pd\/CeO\n                    <jats:sub>2<\/jats:sub>\n                    \/\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst, in which Pd colloids dispersed in a nanoscale CeO\n                    <jats:sub>2<\/jats:sub>\n                    matrix serve as the key building block for the methanol\u2010active component, efficiently catalysing the STD reaction. For Pd\/CeO\n                    <jats:sub>2<\/jats:sub>\n                    \/\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    with a high Pd\u2010CeO\n                    <jats:sub>2<\/jats:sub>\n                    interface concentration, CO conversion and dimethyl ether yield are significantly increased compared to Pd supported on Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    . Systematic investigations using spectroscopic and microscopic techniques reveal the formation of highly dispersed palladium clusters\/particles confined within the nanoparticulate CeO\n                    <jats:sub>2<\/jats:sub>\n                    matrix. The superior catalytic performance in both activity and stability observed for the Pd\/CeO\n                    <jats:sub>2<\/jats:sub>\n                    \/\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    in the STD reaction stems from the active cationic palladium interfacial species and the presence of adjacent O vacancies.\n                  <\/jats:p>","DOI":"10.1002\/anie.202423273","type":"journal-article","created":{"date-parts":[[2025,2,25]],"date-time":"2025-02-25T19:57:46Z","timestamp":1740513466000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Single\u2010Step Synthesis of Dimethyl Ether from Syngas over Nanoparticle\u2010Derived Bifunctional Pd\/CeO\n                    <sub>2<\/sub>\n                    \/Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Catalysts"],"prefix":"10.1002","volume":"64","author":[{"given":"Bing","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Catalysis Research and Technology (IKFT) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 D-76344 Eggenstein-Leopoldshafen"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zairan","family":"Yu","sequence":"additional","affiliation":[{"name":"Institute of Functional Interfaces (IFG) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 D-76344 Eggenstein-Leopoldshafen"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Functional Interfaces (IFG) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 D-76344 Eggenstein-Leopoldshafen"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8026-1048","authenticated-orcid":false,"given":"Nicola","family":"Da Roit","sequence":"additional","affiliation":[{"name":"Institute of Catalysis Research and Technology (IKFT) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 D-76344 Eggenstein-Leopoldshafen"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6034-8146","authenticated-orcid":false,"given":"Dieter","family":"Schild","sequence":"additional","affiliation":[{"name":"Institute for Nuclear Waste Disposal (INE) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 D-76344 Eggenstein-Leopoldshafen"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Zimmermann","sequence":"additional","affiliation":[{"name":"Institute of Catalysis Research and Technology (IKFT) Karlsruhe Institute of Technology 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