{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T17:36:27Z","timestamp":1791480987742,"version":"4.3.4"},"reference-count":64,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T00:00:00Z","timestamp":1742860800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFE0107900"],"award-info":[{"award-number":["2022YFE0107900"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB3803600"],"award-info":[{"award-number":["2022YFB3803600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52302315"],"award-info":[{"award-number":["52302315"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22461142136"],"award-info":[{"award-number":["22461142136"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["22230780200"],"award-info":[{"award-number":["22230780200"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["20DZ2250400"],"award-info":[{"award-number":["20DZ2250400"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["222201717003"],"award-info":[{"award-number":["222201717003"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,5,19]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Direct chemical conversion of plastic waste into low\u2010carbon oxygenates, rather than carbon dioxide, with renewable energy, is important yet challenging. Due to high C\u2500X (X\u2550C, H, N) bond energy, fully optimized catalysts are required to enable precise bond cleavage for boosted efficiency and selectivity. Here, adaptable and recyclable molybdenum peroxide photocatalysts that demonstrate chemical scissors for the selective conversion of polyamide to alcohols are reported. It shows that dimensionally adaptable Mo(+5.8)\u2010(O<jats:sub>2<\/jats:sub>) is activated via a ligand\u2010to\u2010metal charge transfer (LMCT) process for localized catalysis to precisely cleave C\u2500X bonds into C<jats:sub>2<\/jats:sub> and C<jats:sub>1<\/jats:sub> alcohols. The additional hydrogen peroxide facilitates the activation and regeneration of the catalytic scissors. These scissors ultimately cut PA6 into methanol with an efficiency of 2.55\u00a0mmol\u00a0L<jats:sup>\u22121<\/jats:sup>\u00a0h<jats:sup>\u22121<\/jats:sup> and a selectivity of 82.4\u00a0%. This work provides insights into the role of adaptable metal peroxides in precisely cutting C\u2500X bonds, which benefits chemical conversion of plastic wastes.<\/jats:p>","DOI":"10.1002\/anie.202423766","type":"journal-article","created":{"date-parts":[[2025,3,14]],"date-time":"2025-03-14T04:15:16Z","timestamp":1741925716000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Activating Molybdenum Peroxide Scissors for Converting Polyamide Plastic into Low Carbon Alcohols"],"prefix":"10.1002","volume":"64","author":[{"given":"Miao","family":"Kan","sequence":"first","affiliation":[{"name":"Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center School of Chemistry and Molecular Engineering East China University of Science and Technology130  1130 Meilong Road Shanghai 200237 P.R. China"},{"name":"Shanghai Engineering Research Center for Multimedia Environmental Catalysis and Resource Utilization East China University of Science and Technology  130 Meilong Road Shanghai 200237 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Tao","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center School of Chemistry and Molecular Engineering East China University of Science and Technology130  1130 Meilong Road Shanghai 200237 P.R. China"},{"name":"Shanghai Engineering Research Center for Multimedia Environmental Catalysis and Resource Utilization East China University of Science and Technology  130 Meilong Road Shanghai 200237 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weijie","family":"Zhuang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center School of Chemistry and Molecular Engineering East China University of Science and Technology130  1130 Meilong Road Shanghai 200237 P.R. China"},{"name":"Shanghai Engineering Research Center for Multimedia Environmental Catalysis and Resource Utilization East China University of Science and Technology  130 Meilong Road Shanghai 200237 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiqun","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center School of Chemistry and Molecular Engineering East China University of Science and Technology130  1130 Meilong Road Shanghai 200237 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Wan","sequence":"additional","affiliation":[{"name":"Synthetic Materials and Functional Devices Max Planck Institute of Microstructure Physics  06120 Halle Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials and School of Materials Science and Engineering Zhejiang University  Hangzhou Zhejiang 310027 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinlong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center School of Chemistry and Molecular Engineering East China University of Science and Technology130  1130 Meilong Road Shanghai 200237 P.R. China"},{"name":"Shanghai Engineering Research Center for Multimedia Environmental Catalysis and Resource Utilization East China University of Science and Technology  130 Meilong Road Shanghai 200237 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0190-4"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0141-3910(98)00037-8"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.20230154"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0046"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00648-4"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-022-00411-8"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaq0324"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abo4626"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05675"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC01872E"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42246-x"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-3861(97)00414-X"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00403"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2023.118729"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00688J"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac011"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.21"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2020.122908"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c01286"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0090-9"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500766"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c01350"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37818-w"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201701619"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9093172"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC02658A"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.54.293"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature02036"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1921536117"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b04711"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114242"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c01053"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC02550C"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtelec.2023.100078"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1134\/S1070427210110170"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC06513A"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.57.2721"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1017\/S0885715618000118"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1017\/S0885715619000095"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2022.02.016"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2215189120"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202300411"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00210E"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2022.125495"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2023.100607"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1740588"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.32.186"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.41.49"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40432-5"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-023-00225-y"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/a908800h"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1013801531939"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c02609"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0038-1098(85)80025-9"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.05.003"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE01408F"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915766"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.07.113"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03605"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121940"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06872"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.10.035"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01278-2"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/elan.1140091411"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202423766","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,22]],"date-time":"2025-09-22T07:59:28Z","timestamp":1758527968000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202423766"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,25]]},"references-count":64,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2025,5,19]]}},"alternative-id":["10.1002\/anie.202423766"],"URL":"https:\/\/doi.org\/10.1002\/anie.202423766","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,25]]},"assertion":[{"value":"2024-12-05","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-14","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202423766"}}