{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,4]],"date-time":"2026-11-04T21:48:04Z","timestamp":1793828884545,"version":"4.6.1"},"reference-count":38,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2025,4,24]],"date-time":"2025-04-24T00:00:00Z","timestamp":1745452800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22032006"],"award-info":[{"award-number":["22032006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52322506"],"award-info":[{"award-number":["52322506"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Traditional synthesis methods for polyzwitterionic hydrogels involve harsh conditions, such as thermal or UV irradiation, prolonged durations, and high monomer concentrations. Herein, we address these challenges at the meantime by proposing a novel chemical method, called hydration\u2010shielding accelerated self\u2010catalytic polymerization (HS\u2010A\u2010RP), facilitating the preparation of polyzwitterionic hydrogels. The discovery is that polyvinyl alcohol (PVA) chains can generate hydration shielding around hydrated zwitterionic monomers, promoting their effective aggregation and rapid crosslinking polymerization under the assistance of silver ions (Ag\n                    <jats:sup>+<\/jats:sup>\n                    )\u2010potassium persulfate (S\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>8<\/jats:sub>\n                    <jats:sup>2\u2010<\/jats:sup>\n                    ) redox catalyst. The HS\u2010A\u2010RP method performs under mild condition (\u22125\u00a0\u00b0C to 37\u00a0\u00b0C) without extra energy, overcomes the critical monomer polymerization concentration limitation (wt%: 0.3%), and completes within an ultrashort polymerization time (&lt;60\u00a0s). The prepared polyzwitterionic hydrogels possesses a denser network and superior mechanical properties compared to those prepared by traditional thermal\/UV methods, exhibiting good antiswelling behavior, excellent lubrication performance, and significant antibacterial and anti\u2010fouling properties. These significant advances endow HS\u2010A\u2010RP with attractive application potentials in manufacturing functional hydrogel coatings for biomedical device, in situ encapsulation of thermally sensitive materials, and excellent sand fixation abilities. Moreover, HS\u2010A\u2010RP method is suitable for scalable manufacture and decorative coating of polyzwitterionic hydrogels on diverse substrates in extreme environmental conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202424129","type":"journal-article","created":{"date-parts":[[2025,4,15]],"date-time":"2025-04-15T06:43:36Z","timestamp":1744699416000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Scalable Preparation of Polyzwitterionic Hydrogels Based on Hydration Shielding\u2010Accelerated Redox Self\u2010Catalytic Polymerization (HS\u2010A\u2010RP)"],"prefix":"10.1002","volume":"64","author":[{"given":"Renjie","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lunkun","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"School of Advanced Manufacturing Nanchang University Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunlei","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"RIKEN Center for Emergent Matter Science 2\u20101 Hirosawa, Wako Saitama 351\u20100198 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiyi","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoduo","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"Shandong Laboratory of Advanced Materials and Green Manufacture at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering Yantai 264006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Advanced Manufacturing Nanchang University Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuanhong","family":"Ma","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"},{"name":"Shandong Laboratory of Advanced Materials and Green Manufacture at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering Yantai 264006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,24]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00344"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/scitranslmed.3004120"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33081-7"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1233"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.actbio.2017.08.007"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TB02477K"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010675"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11364-w"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.17822"},{"key":"e_1_2_8_10_1","volume-title":"Intermolecular and Surface Forces","author":"Israelachvili J. 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