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However, no report exists on the \u201casymmetric molecular interaction\u201d induced by symmetric molecular structure in nonfullerene acceptors. Herein, we showcase that 2D fluorophenyl outer groups in symmetric 4FY promote dipole\u2010driven self\u2010assembly through asymmetric molecular interactions, resulting in a tighter packed structure than Y6 with the same symmetric geometry. Such unique properties lead to high\u2010performance layer\u2010by\u2010layer OSCs, accompanied by simultaneously reduced energy and recombination losses and improved charge\u2010related characteristics. ST\u2010OSCs based on PCE10\u20102F\/4FY achieve notable power conversion efficiency (PCE) of 10.81%, average visible transmittance of 45.43%, and light utilization efficiency (LUE) of 4.91%. Moreover, exceptional diurnal cycling stability is observed in the ST\u2010OSCs based on PCE10\u20102F\/4FY with much prolonged\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>80<\/jats:sub>\n                    up to 134\u00a0h, which is about 17 times greater than the reference PCE10\u20102F\/Y6. Lastly, we fabricate highly efficient semitransparent organic solar modules based on PCE10\u20102F\/4FY (active area of 18 cm\n                    <jats:sup>2<\/jats:sup>\n                    ), which shows PCE of 6.78% and the highest LUE of 3.10% to date for all\u2010narrow bandgap semitransparent organic solar modules. This work demonstrates that asymmetry\u2010driven molecular interactions can be leveraged to fabricate large\u2010area ST\u2010OSCs that are efficient and stable under realistic operating conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202424287","type":"journal-article","created":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T09:14:51Z","timestamp":1744190091000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Efficient Semitransparent Organic Solar Modules with Exceptional Diurnal Stability Through Asymmetric Interaction Induced by Symmetric Molecular Structure"],"prefix":"10.1002","volume":"64","author":[{"given":"Sangjin","family":"Yang","sequence":"first","affiliation":[{"name":"School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  50 UNIST\u2010gil, Ulju\u2010gun Ulsan 44919 South 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Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lian","family":"Zhong","sequence":"additional","affiliation":[{"name":"School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  50 UNIST\u2010gil, Ulju\u2010gun Ulsan 44919 South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shanshan","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Energy &amp; Power Engineering MOE Key Laboratory of Low\u2010Grade Energy Utilization Technologies and Systems CQU\u2010NUS Renewable Energy Materials &amp; Devices Joint Laboratory Chongqing University  Chongqing 400044 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunfeng","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid State Microstructures and School of Physics Nanjing University  Nanjing 210093 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