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Here, we develop an efficient PdZn\u2212ZnO\/TiO\n                    <jats:sub>2<\/jats:sub>\n                    catalyst by engineering lattice dislocation structures of TiO\n                    <jats:sub>2<\/jats:sub>\n                    support. We discover that this modification orders irregularly arranged atoms in TiO\n                    <jats:sub>2<\/jats:sub>\n                    to stabilize crystal lattice, and consequently weakens electronic interactions with supported active phases. It facilitates the transformation of metallic Pd into PdZn alloy, effectively suppressing CO production through inhibiting the reverse water\u2010gas shift reaction mediated by the carboxylate pathway on Pd\n                    <jats:sup>0<\/jats:sup>\n                    sites. Moreover, it enables the efficient transfer of hydrogen species via hydrogen spillover from PdZn alloy to ZnO for compensating the poor hydrogen dissociation ability of ZnO, thereby creating both more oxygen vacancies essential for CO\n                    <jats:sub>2<\/jats:sub>\n                    activation and a hydroxyl\u2010rich environment conducive to hydrogenation of intermediates. These collective modifications on PdZn\u2212ZnO dual sites synergistically induce the propensity of the formate pathway for methanol synthesis. Consequently, compared to the unmodified catalyst, our as\u2010designed catalyst increases methanol selectivity from 64.2 to 80.0\u2009%, reduces CO selectivity from 35.0 to 19.8\u2009%, and achieves an impressive methanol space\u2010time yield of 9028.0\u2005mg\n                    <jats:sub>MeOH<\/jats:sub>\n                    g\n                    <jats:sub>Pd+Zn<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a similar CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion (~8.0\u2009%).\n                  <\/jats:p>","DOI":"10.1002\/anie.202424435","type":"journal-article","created":{"date-parts":[[2024,12,29]],"date-time":"2024-12-29T22:19:18Z","timestamp":1735510758000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Engineering Lattice Dislocations of TiO\n                    <sub>2<\/sub>\n                    Support of PdZn\u2212ZnO Dual\u2010Site Catalysts to Boost CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol"],"prefix":"10.1002","volume":"64","author":[{"given":"Xiaoshen","family":"Li","sequence":"first","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingpeng","family":"Cheng","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. China"},{"name":"KAUST Catalysis Center (KCC) Physical Sciences and Engineering Division King Abdullah University of Science and Technology (KAUST)  Thuwal 23955-6900 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingtian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunhao","family":"Liu","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Pan","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Liu","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueyang","family":"Jiang","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering School of Chemical Engineering &amp; Technology Tianjin University  Tianjin 300072 P. R. 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