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Herein, two pure organic metal\u2010free room\u2010temperature phosphorescence (RTP) materials were developed using a covalent trimerization strategy of thianthrene (TA), which exhibit high oxygen sensitivity and fluorescence\u2010RTP separated dual emission due to the moderate spin\u2010orbit coupling (SOC). Compared with traditional metal\u2010organic complexes, the oxygen sensitivity of RTP is improved by about two orders of magnitude, especially facilitating accurate quantitative detection of low\u2010concentration oxygen. Leveraging oxygen quenching\u2010induced changes in emission color and intensity, coupled with computer\u2010assisted image processing, a simple oxygen monitoring device was established to realize real\u2010time and accurate detection of low\u2010concentration oxygen, promoting the industrial practical application in many related fields.<\/jats:p>","DOI":"10.1002\/anie.202424669","type":"journal-article","created":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T03:21:16Z","timestamp":1744168876000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Highly Sensitive Thianthrene Covalent Trimer Room\u2010Temperature Phosphorescent Materials for Low\u2010Concentration Oxygen Detection"],"prefix":"10.1002","volume":"64","author":[{"given":"Zhiqiang","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun Jilin 130012 P.R. 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