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This catalytic process is enabled by a series of Bi\u2010based organometallic transformations, including an unprecedented transmetalation of aryl silicates to Bi(III) complexes and the formal migratory insertion of sulfur dioxide (SO\n                    <jats:sub>2<\/jats:sub>\n                    ) into the Bi\u2010C bond. The protocol is compatible with a wide range of anionic and neutral Ar\u2010Si compounds, including heterocycles. Stoichiometric investigations of individual organometallic steps provide strong evidence supporting a Bi\u2010redox\u2010neutral catalytic cycle.\n                  <\/jats:p>","DOI":"10.1002\/anie.202424698","type":"journal-article","created":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T00:03:16Z","timestamp":1739232196000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Aryl Silicon Nucleophiles in Bismuth Catalysis"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-2107-1096","authenticated-orcid":false,"given":"Teresa","family":"Faber","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-1640-2870","authenticated-orcid":false,"given":"Sophia","family":"Engelhardt","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4152-7098","authenticated-orcid":false,"given":"Josep","family":"Cornella","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,28]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"For recent reviews see:"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12816"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04897"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315046"},{"key":"e_1_2_3_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202315046"},{"key":"e_1_2_3_5_1","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07044"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01229-7"},{"key":"e_1_2_3_8_2","author":"Mato M.","year":"2024","journal-title":"Angew. 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