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For the first family M could be either nickel or cobalt, and RE = Pr, Nd, Sm, Eu, and Gd; while the latter features the highest nuclearity of transition\u2010rare earth metal clusters. Characterized by their cube\u2010like, hollow structures, these clusters exhibit the ability to absorb N\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    . Besides, these clusters can be dissolved in both aqueous and acetonitrile\/methanol solutions, and capable of acting as homogeneous catalysts for converting CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO under visible light. The gadolinium analogues of these clusters all show turnover numbers over 10000 and turnover frequencies over 1\u2005s\n                    <jats:sup>\u22121<\/jats:sup>\n                    . In particular, the nickel based bimetallic cluster (PCC\u2010216NG) demonstrates nearly 100\u2009% selectivity for the reduction product, which may open a new direction for the design and development of PCCs based catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202424805","type":"journal-article","created":{"date-parts":[[2025,1,25]],"date-time":"2025-01-25T10:00:10Z","timestamp":1737799210000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Porous 3\u2009d\u20104\u2009f Coordination Clusters for Selective Visible\u2010Light Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction to CO"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6396-9300","authenticated-orcid":false,"given":"Wei\u2010Peng","family":"Chen","sequence":"first","affiliation":[{"name":"Frontier Institute of Science and Technology, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Key Laboratory of Electronic Devices and Materials Chemistry, School of Chemical Engineering and Technology, Instrument Analysis Center Xi'an Jiaotong University  Xi'an 710054 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai\u2010Peng","family":"Bai","sequence":"additional","affiliation":[{"name":"Frontier Institute of Science and Technology, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Key Laboratory of Electronic Devices and Materials Chemistry, School of Chemical Engineering and Technology, Instrument Analysis Center Xi'an Jiaotong University  Xi'an 710054 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Man\u2010Ting","family":"Lv","sequence":"additional","affiliation":[{"name":"Frontier Institute of Science and Technology, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Key Laboratory of Electronic Devices and Materials Chemistry, School of 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