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The base mediated racemization of an intermediate cyclohexenone to facilitates a dynamic kinetic resolution, affording highly enantioenriched cyclohexanes in excellent yields, which could be further functionalized by removal of the Ph* group. DFT modelling revealed the mode of enantioinduction to be a stepwise process comprising of a hydride transfer and a coordination change to a \u03c0\u2010allylic enolate complex with the iridium catalyst.<\/jats:p>","DOI":"10.1002\/anie.202424959","type":"journal-article","created":{"date-parts":[[2025,2,5]],"date-time":"2025-02-05T08:34:36Z","timestamp":1738744476000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7046-3295","authenticated-orcid":false,"given":"Daniella M. 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