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However, the clean, efficient and convenient synthesis of this compound remains challenging. This work demonstrates a rationally designed electron\u2010self\u2010supplied catalytic system capable of generating H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> from water and atmospheric oxygen without extra energy input. This catalytic system is made of a ZnO coating containing oxygen vacancies and a Zn substrate. The ZnO catalyst layer obtains electrons from the Zn substrate to synthesize H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>. The H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> concentration produced by this catalytic system is up to 17.9\u2005mM without any secondary processing. This remarkably high concentration is attributed to the formation of a liquid film on the hydrophilic ZnO surface that promotes the oxygen reduction reaction by accelerating the transfer of oxygen from the ambient air to the catalyst surface. By integrating with atmospheric fog collection, this system can continuously collect H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> directly from the air.<\/jats:p>","DOI":"10.1002\/anie.202424984","type":"journal-article","created":{"date-parts":[[2025,2,1]],"date-time":"2025-02-01T12:43:47Z","timestamp":1738413827000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["A ZnO\u2010based Catalytic System for the Synthesis of Hydrogen Peroxide from Air"],"prefix":"10.1002","volume":"64","author":[{"given":"Lan","family":"Wang","sequence":"first","affiliation":[{"name":"Department Institute of Biomedical Engineering College of Medicine Southwest Jiaotong University  Chengdu 610031, Sichuan P.\u2005R. China"},{"name":"Department Key Laboratory of Advanced Technologies of Materials Ministry of Education School of Materials Science and Engineering Southwest Jiaotong University  Chengdu 610031 P.\u2005R. 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