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Herein, we have successfully constructed a photocatalyst, the Fe\u2010doped ZnO hollow polyhedron (Fe\/ZnOHP), for the highly selective photoconversion of CH\n                    <jats:sub>4<\/jats:sub>\n                    to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH under mild conditions. In situ experiments and density functional theory calculations confirmed that the introduction of Fe was able to decrease the energy level of the O 2\n                    <jats:italic>p<\/jats:italic>\n                    orbital, which passivated the activity of lattice oxygen in ZnO nanocrystals. This passivation effect greatly weakened the interaction between *CH\n                    <jats:sub>3<\/jats:sub>\n                    and lattice oxygen, thus facilitating the conversion of *CH\n                    <jats:sub>3<\/jats:sub>\n                    O to *CH\n                    <jats:sub>3<\/jats:sub>\n                    intermediate rather than the direct desorption of *CH\n                    <jats:sub>3<\/jats:sub>\n                    O. As a result, Fe\/ZnOHP exhibited excellent CH\n                    <jats:sub>3<\/jats:sub>\n                    OH generation rate (ca. 1009\u2005\u03bcmol\u2009g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and selectivity (ca. 96\u2009%) in the photocatalytic conversion of CH\n                    <jats:sub>4<\/jats:sub>\n                    at room temperature and low pressure.\n                  <\/jats:p>","DOI":"10.1002\/anie.202425186","type":"journal-article","created":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:09:07Z","timestamp":1736899747000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":56,"title":["Passivating Lattice Oxygen in ZnO Nanocrystals to Reduce its Interactions with the Key Intermediates for a Selective Photocatalytic Methane Oxidation to Methanol"],"prefix":"10.1002","volume":"64","author":[{"given":"Ruimin","family":"Lan","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuofeng","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology Sun Yat-sen University University of Technology  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"School of Basic Medical Sciences Guangzhou University of Chinese Medicine  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kui","family":"Shen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Guangdong University of Petrochemical Technology  Maoming Guangdong 525000 China"},{"name":"Guangdong Provincial Key Laboratory of Advanced Green Lubricating Materials  Maoming Guangdong 525000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Hou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510640 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