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However, supramolecularly designed organic thin\u2010film transistor (OTFT) devices using hydrogen bonds have not been sufficiently developed. This is because of the reduced solubility caused by introducing hydrogen bond sites and the difficulty in controlling molecular orientations and packing structures. Herein, we report a reasonable strategy for the formation of hydrogen\u2010bonded semiconductor thin films of a tetrabenzoporphyrin derivative with amide groups using the thermal precursor approach. The thin films are successfully fabricated by thermal conversion of the corresponding precursor in the film state. Assembly structure with a hydrogen\u2010bond network is revealed by the combination of X\u2010ray diffraction and infrared p\u2010polarized multiple\u2010angle incidence resolution spectrometry. The OTFT devices exhibit high hole mobility of 0.25 cm\n                    <jats:sup>2<\/jats:sup>\n                    V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    among hydrogen\u2010bonded OTFTs reported previously. Notably, we unveiled the high thermal stability of semiconductor films without decreasing device performance in air up to 250\u00a0\u00b0C. This strategy can become a key methodology to form hydrogen\u2010bond\u2010directed organic electronic devices, namely supramolecular devices.\n                  <\/jats:p>","DOI":"10.1002\/anie.202425188","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T00:42:30Z","timestamp":1741740150000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Hydrogen\u2010Bond\u2010Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach"],"prefix":"10.1002","volume":"64","author":[{"given":"So","family":"Ueno","sequence":"first","affiliation":[{"name":"Institute for Chemical Research Kyoto University  Gokasho Uji Kyoto 611\u20100011 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mitsuaki","family":"Yamauchi","sequence":"additional","affiliation":[{"name":"Institute for Chemical Research Kyoto University  Gokasho Uji Kyoto 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