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However, the use of unsymmetrical 1,3\u2010disubstituted allyl electrophiles has been severely constrained by the challenges of achieving both regio\u2010 and stereoselectivity simultaneously. Herein, we present \u03b3\u2010silyl\u2010substituted allyl acetates as highly effective electrophiles for a regio\u2010 and enantioconvergent hydroallylation, enabling the construction of vicinal stereogenic centers. This method delivers allylated products in 44%\u201393% yield with 79:21 to &gt;95:5 dr and 88% to &gt;99% ee. Additionally, the silyl group in the products can be readily converted into other functional groups, such as acyl and aryl groups, enhancing their synthetic utility.<\/jats:p>","DOI":"10.1002\/anie.202425256","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T06:08:01Z","timestamp":1741759681000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Regio\u2010 and Enantioconvergent Hydroallylation of Acrylates Enabled by \u03b3\u2010Silyl\u2010Substituted Allyl Acetates"],"prefix":"10.1002","volume":"64","author":[{"given":"Hirotsugu","family":"Suzuki","sequence":"first","affiliation":[{"name":"Tenure\u2010Track Program for Innovative Research University of Fukui  3\u20109\u20101 Bunkyo, Fukui\u2010shi Fukui 910\u20108507 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ryoichi","family":"Nishikawa","sequence":"additional","affiliation":[{"name":"Department of 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