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However, the difficult water dissociation process for the Volmer step (H\n                    <jats:sub>2<\/jats:sub>\n                    O\u00a0\u2192\u00a0H*\u00a0+\u00a0OH*) and the subsequent unsuitable OH* adsorption energy on nonprecious metal\u2010based catalysts severely reduce the kinetics of HER. Herein, the universal synthesis for a series of transition metal (Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W)\u2010based boride@sulfide heterostructured catalysts is realized by using the molten\u2010salt method to conduct the in situ boronization of commercial sulfides. Significantly, WB\n                    <jats:sub>2<\/jats:sub>\n                    @WS\n                    <jats:sub>2<\/jats:sub>\n                    heterostructured catalyst exhibits excellent catalytic activity and stability for HER. Balancing interfacial atom orbit hybridization between W(\n                    <jats:italic>d<\/jats:italic>\n                    )\u2010B(\n                    <jats:italic>s<\/jats:italic>\n                    ,\n                    <jats:italic>p<\/jats:italic>\n                    ) and W(\n                    <jats:italic>d<\/jats:italic>\n                    )\u2010S(\n                    <jats:italic>s<\/jats:italic>\n                    ,\n                    <jats:italic>p<\/jats:italic>\n                    ) at WB\n                    <jats:sub>2<\/jats:sub>\n                    @WS\n                    <jats:sub>2<\/jats:sub>\n                    heterostructured interface enhances the built\u2010in electric field. In situ Raman spectroscopy and density functional theory calculation results reveal that the strong built\u2010in electric field in WB\n                    <jats:sub>2<\/jats:sub>\n                    @WS\n                    <jats:sub>2<\/jats:sub>\n                    optimizes the adsorption and desorption of OH* intermediate, reducing the energy barrier of the rate\u2010determining step (OH* desorption step), and thus favoring the enhancement of catalytic performance toward HER.\n                  <\/jats:p>","DOI":"10.1002\/anie.202425657","type":"journal-article","created":{"date-parts":[[2025,4,15]],"date-time":"2025-04-15T10:45:19Z","timestamp":1744713919000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Enhancing Built\u2010In Electric Field via Balancing Interfacial Atom Orbit Hybridization at Boride@Sulfide Heterostructure for Hydrogen Evolution 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