{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T16:10:51Z","timestamp":1792080651964,"version":"4.4.0"},"reference-count":47,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T00:00:00Z","timestamp":1740096000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T00:00:00Z","timestamp":1740096000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373181 52173164"],"award-info":[{"award-number":["52373181 52173164"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007847","name":"Natural Science Foundation of Jilin Province","doi-asserted-by":"publisher","award":["20230101038JC"],"award-info":[{"award-number":["20230101038JC"]}],"id":[{"id":"10.13039\/100007847","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,3,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Advancements in crystal engineering have enabled the precise tuning of the physical properties of organic crystals, thereby enhancing their potential in advanced optoelectronics. Here, we design an organic compound which crystallizes into distinct polymorphs with contrasting luminescent and mechanical behaviors. Controlled growth conditions yield flexible (Cry\u2010\n                    <jats:bold>O<\/jats:bold>\n                    : orange fluorescence) and brittle (Cry\u2010\n                    <jats:bold>Y<\/jats:bold>\n                    : yellow fluorescence) crystals which exhibit unique fluorescence shifts and reversible spectral changes between room and low temperatures, alongside unidirectional phase transitions upon thermal stimulation. The optical and mechanical differences between the polymorphs\n                    <jats:bold>O<\/jats:bold>\n                    and\n                    <jats:bold>Y<\/jats:bold>\n                    stem from their distinct molecular packing arrangements and intermolecular interactions. Notably, Cry\u2010\n                    <jats:bold>O<\/jats:bold>\n                    undergoes sequential phase transitions upon heating to 98 and 132\u2009\u00b0C, enabling the creation of a ternary \u201cpseudo\u2010heterojunction\u201d structure, facilitating the integration of multiple functional phases into a single material. These findings not only enhance the understanding of structure\u2013property relationships of organic materials but also demonstrate the potential of polymorphism\u2010driven property tuning for optoelectronic devices, thermal management systems, and optical sensors.\n                  <\/jats:p>","DOI":"10.1002\/anie.202500151","type":"journal-article","created":{"date-parts":[[2025,2,13]],"date-time":"2025-02-13T05:46:08Z","timestamp":1739425568000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["An Organic Crystalline Ternary Pseudo\u2010Heterojunction with Contrasting Luminescent and Mechanical Properties Prepared by Thermotropic Phase Transition"],"prefix":"10.1002","volume":"64","author":[{"given":"Jianqun","family":"Qi","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Qianjin Street, 2699 Changchun P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linfeng","family":"Lan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Qianjin Street, 2699 Changchun P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0219-3948","authenticated-orcid":false,"given":"Hongyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Qianjin Street, 2699 Changchun P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,21]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100380z"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b907999h"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar800057k"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/B813123F"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-39162-5"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53196-3"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217329"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302929"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003820"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC05044G"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-52187-8"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108441"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c01659"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420139"},{"key":"e_1_2_3_15_1","volume":"63","author":"Chen Q.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.4c01332"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207431"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700813"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.08.019"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201811313"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c04560"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2848"},{"key":"e_1_2_3_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC04132F"},{"key":"e_1_2_3_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201204604"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1080\/0889311X.2017.1420649"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.3c00908"},{"key":"e_1_2_3_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-47881-6"},{"key":"e_1_2_3_28_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.022.202202278"},{"key":"e_1_2_3_29_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.200329"},{"key":"e_1_2_3_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7QM00617A"},{"key":"e_1_2_3_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TC01301F"},{"key":"e_1_2_3_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NJ00588F"},{"key":"e_1_2_3_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.1c01459"},{"key":"e_1_2_3_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c00225"},{"key":"e_1_2_3_35_1","first-page":"3849","volume":"10","author":"Tang B.","year":"2022","journal-title":"J. Mater. Chem. C"},{"key":"e_1_2_3_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CE02550H"},{"key":"e_1_2_3_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403914"},{"key":"e_1_2_3_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802785"},{"key":"e_1_2_3_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC01358K"},{"key":"e_1_2_3_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12363"},{"key":"e_1_2_3_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2019.06.018"},{"key":"e_1_2_3_42_1","unstructured":"Deposition numbers 2401422 (for Cry-O 100\u2005K) 2401423 (for Cry-Y 100\u2005K) 2401424 (for Cry-O 298\u2005K) and 2401427 (for Cry-Y 298\u2005K) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structuresservice."},{"key":"e_1_2_3_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC01841H"},{"key":"e_1_2_3_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00469G"},{"key":"e_1_2_3_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00425"},{"key":"e_1_2_3_46_1","author":"Lan L.","year":"2024","journal-title":"CCS Chem."},{"key":"e_1_2_3_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201500106"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202500151","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202500151","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202500151","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T11:37:22Z","timestamp":1788349042000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202500151"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,21]]},"references-count":47,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2025,3,24]]}},"alternative-id":["10.1002\/anie.202500151"],"URL":"https:\/\/doi.org\/10.1002\/anie.202500151","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,21]]},"assertion":[{"value":"2025-01-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-02-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500151"}}