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Herein, a capping\u2010assisted strategy was presented to control the molecular assembly during the metal\u2010ligand coordination in the solution and to inhibit the long\u2010range of order hence building glass\u2010like CPs (g\u2010CPs) mimicking the polymerization process. 1,3,5\u2010benzene tricarboxylate (BTC) ligand was used to connect the copper cations (Cu\n                    <jats:sup>2+<\/jats:sup>\n                    ) into metal\u2010organic complexes of different Cu: BTC ratios (metal\u2010organic pool) in presence of an excess of triethyl amine as a capping agent. Concentrating the Cu\u2010BTC complexes and further drying under mild conditions induced the decapping process which triggered the random crosslinking between the free carboxylate and Cu\n                    <jats:sup>2+<\/jats:sup>\n                    to form a boundary\u2010free continuous internal structure. The as\u2010prepared Cu\u2010BTC g\u2010CP exhibited an approximately similar fine structure like its crystalline counterpart (HKUST\u20101), which facilitated solvent and thermal\u2010induced crystallization. Due to the internal structure continuity, the g\u2010CP possesses ceramic\u2010like hardness and wear resistance and plastic\u2010like resilience. This capping\u2010assisted strategy has been successfully extended to Ni\u2010BTC and Fe\u2010BTC systems under mild conditions and thus presenting a general method for the formation of glass\u2010like carboxylate\u2010based CPs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202500266","type":"journal-article","created":{"date-parts":[[2025,4,3]],"date-time":"2025-04-03T14:46:51Z","timestamp":1743691611000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["A Capping\u2010assisted Strategy for Synthesis of Glass\u2010like Carboxylate\u2010based Coordination Polymers"],"prefix":"10.1002","volume":"64","author":[{"given":"Mohamed K.","family":"Albolkany","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Department of Environmental Studies, Institute of Graduate Studies and Research Alexandria 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