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However, the challenge of efficiently regulating photogenerated electrons to CO\n                    <jats:sub>2<\/jats:sub>\n                    active sites remains a key hurdle for high\u2010performance CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. Herein, an embedded functional group, ether group is introduced into porphyrin\u2010triazine COFs to regulate the transfer behavior of photogenerated electrons. The ether\u2010embedded COFs (TOT\u2010TAPP, BOD\u2010TAPP and QOB\u2010TAPP) demonstrate significantly faster charge transport and higher photoactivity compared with the corresponding non\u2010ether\u2010embedded counterpart COFs. The theoretical calculations and in situ characterizations reveal that the ether group could not only accelerate the separation of photogenerated charge carriers, but also lead to a more substantial accumulation of electrons at the CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption region (C=N imine bond), thus greatly promoting the efficiency of CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction.\n                  <\/jats:p>","DOI":"10.1002\/anie.202500329","type":"journal-article","created":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T06:42:21Z","timestamp":1739256141000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Ether\u2010Embedded Covalent Organic Frameworks Enable Efficient Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"64","author":[{"given":"Desen","family":"Zhou","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemical Process of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering and Pharmacy Wuhan Institute of Technology  Wuhan 430205 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Process of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering and Pharmacy Wuhan Institute of Technology  Wuhan 430205 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Process of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering and Pharmacy Wuhan Institute of Technology  Wuhan 430205 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tielin","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Process of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering and Pharmacy Wuhan Institute of Technology  Wuhan 430205 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0727-7809","authenticated-orcid":false,"given":"Zhao\u2010Qing","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University"},{"name":"Key Laboratory for Water Quality and Conservation of the Pearl River Delta Guangzhou Key Laboratory for Clean Energy and Materials School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,14]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","author":"Lan X.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_3_2","author":"Li J.","year":"2024","journal-title":"Angew. Chem. Int. 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