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However, the subtle nature of these interactions poses challenges for characterization using standard techniques. Herein, an efficient method of weak binding characterization based on the zero\u2010field splitting of a high\u2010spin probe by electron paramagnetic resonance is presented. Using endofullerene as the high spin center, we achieved direct comparison of the weak binding strengths in\n                    <jats:bold>F\u2010MTPP<\/jats:bold>\n                    (M\u00a0=\u00a0H\n                    <jats:sub>2<\/jats:sub>\n                    , Zn, Ni, and Pd) and\n                    <jats:bold>2F\u20103MTPP<\/jats:bold>\n                    (M\u00a0=\u00a0H\n                    <jats:sub>2<\/jats:sub>\n                    , Ni, Pd, and Pt) through the zero\u2010field splitting parameters. The high\u2010spin resonance spectrum is sensitive to the small variation in the supramolecular structure. By examining fullerene\u2013porphyrin co\u2010crystals with various metal centers and packing arrangements, the relation between intermolecular weak binding and microstructural strain on the fullerene cage is elucidated.\n                  <\/jats:p>","DOI":"10.1002\/anie.202500662","type":"journal-article","created":{"date-parts":[[2025,4,22]],"date-time":"2025-04-22T02:38:17Z","timestamp":1745289497000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Evaluation of Intermolecular Weak Binding Through the Zero\u2010Field Splitting of an Endofullerene High\u2010Spin Probe"],"prefix":"10.1002","volume":"64","author":[{"given":"Qi","family":"Xiong","sequence":"first","affiliation":[{"name":"Spin\u2010X Institute School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 511442 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Yue","family":"Yuan","sequence":"additional","affiliation":[{"name":"Spin\u2010X Institute School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 511442 China"},{"name":"College of Science Hunan Key Laboratory of Mechanism and Technology of Quantum Information National University of Defense Technology  Changsha 410000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You\u2010Chao","family":"Liu","sequence":"additional","affiliation":[{"name":"Spin\u2010X Institute School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of 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School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 511442 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cong\u2010Hui","family":"Wu","sequence":"additional","affiliation":[{"name":"Spin\u2010X Institute School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 511442 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin\u2010Yu","family":"Hui","sequence":"additional","affiliation":[{"name":"Spin\u2010X Institute School of Chemistry and Chemical Engineering Guangdong\u2010Hong Kong\u2010Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 511442 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education School of Chemistry, LIFM, IGCME, GBRCE for Functional Molecular Engineering Sun Yat\u2010Sen University  Guangzhou 510275 China"},{"name":"Spin\u2010X Institute South China University of Technology  Guangzhou 511442 China"},{"name":"Beijing National Laboratory of Molecular Science Beijing Key Laboratory of Magnetoelectric Materials and Devices College of Chemistry and Molecular Engineering Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye\u2010Xin","family":"Wang","sequence":"additional","affiliation":[{"name":"Quantum Science Center of Guangdong\u2010Hong Kong\u2010Macao Greater 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