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To address the challenge, here we proposed a new core\u2013shell design of nanocomposite catalysts comprising of carbon quantum dot (CD)\u2010topped TiO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles encapsulated by polydopamine (PDA) shells, which delivered stable catalytic activity across a pH range of 1\u20139, exhibiting a photocatalytic generation rate of H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    that reached 18.14\u2005mmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in methanol and 8.66\u2005mmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in water. This extraordinary, pH\u2010tolerant photocatalytic generation of H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    was benefited from the innovative use of CDs, interspaced between the TiO\n                    <jats:sub>2<\/jats:sub>\n                    cores and PDA shells, not only as a reservoir of protons to buffer the local acidic microenvironment but also as a proton\/electron dual booster to sustain an excellent kinetic match between the proton and photogenerated electron transfer, thus enabling the O\n                    <jats:sub>2<\/jats:sub>\n                    reduction to selectively proceed via two\u2010electron reaction pathway over a wide pH span.\n                  <\/jats:p>","DOI":"10.1002\/anie.202501357","type":"journal-article","created":{"date-parts":[[2025,2,6]],"date-time":"2025-02-06T22:18:17Z","timestamp":1738880297000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Leveraging Carbon Quantum Dot Spacers as Dual Proton\/Electron Boosters to Upgrade TiO\n                    <sub>2<\/sub>\n                    @Polydopamine Photocatalysts for pH\u2010Resilient Conversion of O\n                    <sub>2<\/sub>\n                    into H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"64","author":[{"given":"Linjia","family":"Li","sequence":"first","affiliation":[{"name":"College of Chemistry Jilin University  Changchun 130012 P.\u2005R. 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