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With unprecedented ease, these reactions allow, in particular, the preparation of sterically demanding phosphanes, which, as ligands, are key components of highly catalytically competent transition metal complexes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202501656","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T05:08:36Z","timestamp":1742879316000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Cl\n                    <sub>3<\/sub>\n                    Al\u2010PH\n                    <sub>3<\/sub>\n                    Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7112-5407","authenticated-orcid":false,"given":"Jan","family":"Oswald","sequence":"first","affiliation":[{"name":"Department of Chemistry and Applied 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