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Herein, a series of coplanar chalcogen\u2010fused heterocycloarenes\n                    <jats:bold>NO<\/jats:bold>\n                    ,\n                    <jats:bold>NS<\/jats:bold>\n                    , and\n                    <jats:bold>NSe<\/jats:bold>\n                    with long branched alkyl chains were synthesized in single\u2010crystal form, and chalcogen atom engineering on heterocycloarenes was investigated in detailed. Sulfur\u2010fused\n                    <jats:bold>NS<\/jats:bold>\n                    exhibits a closest herringbone crystal packing with \u03c0\u2013\u03c0 stacking distance as low as 3.11\u2005\u00c5, resulting in a record\u2010high hole mobility of 3.13\u2005cm\n                    <jats:sup>2<\/jats:sup>\n                    \u2009V\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009s\n                    <jats:sup>\u22121<\/jats:sup>\n                    among all reported ring\u2010shaped OSCs. Remarkably, selenium\u2010fused\n                    <jats:bold>NSe<\/jats:bold>\n                    without intermolecular \u03c0\u2013\u03c0 interactions in its crystalline state, also manifests the second highest mobility of up to 2.11\u2005cm\n                    <jats:sup>2<\/jats:sup>\n                    \u2009V\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009s\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is attributed to the presence of extensive short\u2010range edge\u2010to\u2010face Se\u2026\u03c0 and C\u2212H\u2026\u03c0 interactions. Furthermore, these heterocycloarenes exhibit a selective supramolecular interaction with C\n                    <jats:sub>70<\/jats:sub>\n                    , with the trend in binding constants being:\n                    <jats:bold>NS<\/jats:bold>\n                    &lt;\n                    <jats:bold>NO<\/jats:bold>\n                    &lt;\n                    <jats:bold>NSe<\/jats:bold>\n                    . Overall, this work not only systematically elucidates the role of atom engineering on heterocycloarenes for the first time, but also paves the way for practical applications of the emerging ring\u2010shaped OSC materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202501686","type":"journal-article","created":{"date-parts":[[2025,3,8]],"date-time":"2025-03-08T02:47:04Z","timestamp":1741402024000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Manipulating Crystal Packing in Heterocycloarenes by an Atom Engineering Strategy for High\u2010Mobility Organic Field\u2010Effect Transistors"],"prefix":"10.1002","volume":"64","author":[{"given":"Rong","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Materials Science State Key Laboratory of Molecular Engineering of Polymers Laboratory of Molecular Materials and Devices Fudan University  Shanghai 200438 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