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However, the slow migration of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    ions and their poor cycling stability hinder their practical application in AZIBs. Herein, using a one\u2010pot solvothermal method, the polyoxometalates (POMs) were inserted into the aluminum vanadate interlayer spacing, and a series of novel 3D nanoflower cathode materials (HAVO\u2010MMo\n                    <jats:sub>6<\/jats:sub>\n                    \u2010\n                    <jats:italic>X<\/jats:italic>\n                    ) were successfully fabricated. The unique electron\u2010rich structure of the POMs accelerated the migration of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    on the cathode to obtain a high specific capacity. Owing to the synergistic pillar effect of POMs and HAVO, the interlayer spacing of HAVO\u2010FeMo\n                    <jats:sub>6<\/jats:sub>\n                    \u201050 increased to approximately 14.33\u00a0\u00c5. X\u2010ray absorption fine structure spectroscopy was used to analyze the coordination environments of the cathode materials. A combination of in situ and ex situ characterization techniques demonstrated the storage mechanism of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    during the charge\/discharge process. Furthermore, the experimental results and DFT calculations indicated that the introduction of POMs had the dual function of improving conductivity and reducing the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    migration barrier. Thus, this work provides a new perspective on the synergistic interaction between POMs and metal compounds and offers insights into the design of functionally rich nanomaterials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202501728","type":"journal-article","created":{"date-parts":[[2025,3,4]],"date-time":"2025-03-04T03:32:35Z","timestamp":1741059155000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":74,"title":["Valence Engineering via Polyoxometalate\u2010Induced on Vanadium Centers for Efficient Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Yanfei","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  Yangzhou Jiangsu 225002 P.R. 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