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The [Cl(CO)\u2082Ir\u2010CPC] and [Cl\n                    <jats:sub>3<\/jats:sub>\n                    Ga\u2010CPC] complexes were synthesized, allowing the measurement of their Tolman electronic parameter (TEP) and the sum of Cl\u2500Ga\u2500Cl bond angles (\u2211ClGaCl), respectively. These data highlight their remarkable electron\u2010donating ability. Further insights into its electron\u2010donating properties were gained through theoretical calculations, including analysis of frontier orbitals and proton affinity (PA). Preliminary reactivity investigations demonstrate that the new CPC readily forms adducts with boranes and can effectively stabilize borenium cations. Its strong nucleophilicity enables reactions with carbon dioxide, while its exceptional Br\u00f8nsted basicity allows it to deprotonate imidazolium to generate carbene species.\n                  <\/jats:p>","DOI":"10.1002\/anie.202501955","type":"journal-article","created":{"date-parts":[[2025,3,19]],"date-time":"2025-03-19T06:55:06Z","timestamp":1742367306000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Conversion of Bestmann Ylide into Carbophosphinocarbene"],"prefix":"10.1002","volume":"64","author":[{"given":"Libo","family":"Xiang","sequence":"first","affiliation":[{"name":"Institute for Inorganic Chemistry Institute for Sustainable Chemistry &amp; Catalysis with Boron Julius\u2010Maximilians\u2010Universit\u00e4t W\u00fcrzburg, Am Hubland  W\u00fcrzburg 97074 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