{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T20:38:23Z","timestamp":1792874303058,"version":"4.5.0"},"reference-count":45,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2025,7,22]],"date-time":"2025-07-22T00:00:00Z","timestamp":1753142400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20242025"],"award-info":[{"award-number":["BK20242025"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2242024K40008"],"award-info":[{"award-number":["2242024K40008"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,9,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Dizygotic\u2010atom\u2010site catalysts (DASCs), consisting of multi\u2010atomic dispersed catalytic centers, perform well in several reactions but have poor electrocatalytic activity toward alcohol electro\u2010oxidation. In this study, DASCs of atomically dispersed platinum and palladium on nitrogen\u2010doped carbon nanocages (Pt\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    \/NCNC) are successfully synthesized using an impregnation\u2013adsorption method. The Pt\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    \/NCNC catalyst has higher mass activity toward ethanol and methanol oxidation than commercial Pt\/C and Pd\/C. In contrast, Pt or Pd single\u2010atom catalysts on nitrogen\u2010doped carbon nanocages are virtually inert. Ethanol and methanol on Pt\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    \/NCNC are electro\u2010oxidized to acetate ion and CO\n                    <jats:sub>2<\/jats:sub>\n                    as the final product, respectively. Pt\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    \/NCNC exhibits long\u2010term stability toward ethanol and methanol oxidation due to the absence of the CO intermediate. Ab initio simulations show that Pt\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    \/NCNC optimizes the ethanol oxidation pathway thanks to a lower energy barrier and onset potential than individual single Pt or Pd atom catalysts on NCNC. This study opens a new path to developing advanced DASCs for alcohol oxidation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202502348","type":"journal-article","created":{"date-parts":[[2025,7,22]],"date-time":"2025-07-22T08:07:51Z","timestamp":1753171671000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Dizygotic Atomic Platinum and Palladium on Carbon for High\u2010Performance Ethanol and Methanol Electro\u2010Oxidation"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0284-4146","authenticated-orcid":false,"given":"Zhiqi","family":"Zhang","sequence":"first","affiliation":[{"name":"Key Laboratory of Energy Thermal Conversion and Control (Ministry of Education) School of Energy and Environment Southeast University  Nanjing P.R. China"},{"name":"Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology  Hong Kong P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiapeng","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Advanced Energy Sun\u2010Yat Sen University  Shenzhen P.R. China"},{"name":"Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology  Hong Kong P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shangqian","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering The Hong Kong University of Science and Technology  Hong Kong P.R. China"},{"name":"School of Chemistry and Chemical Engineering Southeast University  Nanjing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhao","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology  Hong Kong P.R. 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