{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T04:16:08Z","timestamp":1792469768436,"version":"4.5.0"},"reference-count":48,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2025,4,17]],"date-time":"2025-04-17T00:00:00Z","timestamp":1744848000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,6,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Glycerol electrooxidation reaction (GEOR) is a promising alternative to the oxygen evolution reaction (OER) in electrolyzers, overcoming the inherent challenges of high energy demand and low\u2010value output of water oxidation. Here, we designed a non\u2010noble metal\u2010based electrocatalyst (CuO@NiBiO\n                    <jats:sub>x<\/jats:sub>\n                    , CNBO) for selective and efficient GEOR. The CNBO catalyst demonstrated high selectivity and achieved nearly 100% GEOR Faradaic efficiency (FE), 80%\u201390% of which is conveyed into formic acid (FA). Bismuth incorporation modified the structure of the mixed oxide, increasing the surface concentration of Ni(III) species and enhancing the GEOR activity. In situ studies confirmed the formation of NiOOH, which is identified as the active site for GEOR and suggests an indirect GEOR mechanism. This study demonstrates the potential of GEOR to replace OER in Carbon dioxide reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) electrolyzers. Depending on the selected CO\n                    <jats:sub>2<\/jats:sub>\n                    RR catalyst (Ag or Sn), we could obtain either an easy\u2010to\u2010separate mixture of high\u2010added value products (CO and FA) or a single product (FA) with FE\n                    <jats:sub>FA<\/jats:sub>\n                    &gt;\u00a085% at both electrodes. Moreover, we demonstrate that replacing OER with GEOR in a CO\n                    <jats:sub>2<\/jats:sub>\n                    RR\u2010electrolyzer can save up to 25% of the electrolysis energy input, while the co\u2010production of FA at both electrodes halves the energy per mole required for its electrosynthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202502617","type":"journal-article","created":{"date-parts":[[2025,4,11]],"date-time":"2025-04-11T08:27:21Z","timestamp":1744360041000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Coupling of CuO@NiBiO\n                    <sub>x<\/sub>\n                    Catalyzed Glycerol Oxidation to Carbon Dioxide Reduction Reaction for Enhanced Energy Efficiency"],"prefix":"10.1002","volume":"64","author":[{"given":"Thi\u2010Hong\u2010Hanh","family":"Le","sequence":"first","affiliation":[{"name":"Istituto Italiano di Tecnologia (IIT)  Via Morego 30 Genova 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