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Herein, we designed three copper(I) cyclic trinuclear units, Cu(I)\u2010CTUs, based covalent metal\u2010organic frameworks (CMOFs) by networking metal clusters with dynamic covalent linkages. These CMOFs deliver a high gold adsorption capacity of 3687\u00a0mg g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , ultra\u2010fast adsorption kinetics (i.e., removal efficiency\u00a0&gt;\u00a099% within\n                    <jats:styled-content>\u00a0<\/jats:styled-content>\n                    20\u00a0s), excellent selectivity and reusability. In addition, they can be readily used for gold extraction from e\u2010waste. Owing to the rich redox properties of Cu\u2010CTUs, these CMOFs show three sorption mechanisms including adsorption, chemical reduction and photocatalytic reduction. Interestingly, the gold\u2010loaded CMOFs can be used as catalysts for hydration of alkynes to ketones with high yields (e.g., up to \u223c 95% for 6 examples).\n                  <\/jats:p>","DOI":"10.1002\/anie.202502749","type":"journal-article","created":{"date-parts":[[2025,4,28]],"date-time":"2025-04-28T22:46:16Z","timestamp":1745880376000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Cyclic Trinuclear Units Based Covalent Metal\u2010Organic Frameworks for Gold Recovery"],"prefix":"10.1002","volume":"64","author":[{"given":"Jie","family":"Luo","sequence":"first","affiliation":[{"name":"College of Chemistry and Materials Science Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University  Guangzhou 510632 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Tong","family":"Lin","sequence":"additional","affiliation":[{"name":"College of Chemistry 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