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However, the selectivity toward phenol is often poor due to the ring\u2010opening reaction induced by the superoxide radical (\u22c5O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), which is predominantly produced from the single\u2010electron reduction of O\n                    <jats:sub>2<\/jats:sub>\n                    . Herein, we demonstrate that introducing abundant oxygen vacancies (OVs) on the surface of titanium dioxide (TiO\n                    <jats:sub>2<\/jats:sub>\n                    ) facilitates the activation of O\n                    <jats:sub>2<\/jats:sub>\n                    through a two\u2010electron reduction process instead of a single\u2010electron reduction. This effectively suppresses the generation of \u22c5O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , thereby reducing phenol decomposition and significantly enhancing the selectivity. In addition, these OVs can trap the electrons to promote chare separation and serve as the adsorption sites for O\n                    <jats:sub>2<\/jats:sub>\n                    activation. As a result, the introduction of abundant OVs on the surface of TiO\n                    <jats:sub>2<\/jats:sub>\n                    not only enhances phenol yield but also importantly improves selectivity toward phenol. This finding enriches our understanding of how OVs influence reaction pathways and product selectivity, providing valuable insights for the design and tailoring of OV\u2010rich photocatalysts for selective organic oxygenations.\n                  <\/jats:p>","DOI":"10.1002\/anie.202502823","type":"journal-article","created":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T05:38:31Z","timestamp":1739770711000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":78,"title":["Oxygen Vacancy\u2010Enhanced Selectivity in Aerobic Oxidation of Benzene to Phenol over TiO\n                    <sub>2<\/sub>\n                    Photocatalysts"],"prefix":"10.1002","volume":"64","author":[{"given":"Shengyang","family":"Zhong","sequence":"first","affiliation":[{"name":"State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou 350108 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