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However, achieving both high selectivity and large current density over wide potential window remains a significant challenge, hindering practical applications. In this study, a Ni\/Fe dual metal\u2010atom catalyst is developed for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction, achieving nearly 100\u2009% CO selectivity across an ultra\u2010wide potential window of 1.6\u2005V, surpassing state\u2010of\u2010the\u2010art catalysts. Remarkably, this high CO selectivity is maintained above 98\u2009% even after 100\u2005hours of continuous operation at an industrial current density of 200\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , demonstrating excellent long\u2010term stability. When integrated into a solar electricity\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction coupled 5\u2010hydroxymethylfurfural oxidation system, nearly 100\u2009% CO Faradaic efficiency and 90\u2009% 2,5\u2010furandicarboxylic acid yield are simultaneously obtained. Theoretical calculations reveal that the rate\u2010limiting step for the CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction varies with the applied potential, and the synergistic interaction between Ni and Fe atoms effectively lowers the limiting energy barrier. This work offers valuable insights for the strategic design and synthesis of catalysts with high activity and selectivity across wide potential window, providing a versatile platform for coupling CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction with diverse anodic biomass oxidation reactions and renewable energy sources.\n                  <\/jats:p>","DOI":"10.1002\/anie.202502846","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T03:20:13Z","timestamp":1741749613000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Integrated Electrochemical Biomass Oxidation and CO\n                    <sub>2<\/sub>\n                    Reduction over Ultra\u2010wide Potential Window"],"prefix":"10.1002","volume":"64","author":[{"given":"Chenbao","family":"Lu","sequence":"first","affiliation":[{"name":"School of Environmental Science and Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"The Soft2D Lab, State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"Frontiers Science Center for Transformative Molecules Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  429 Zhangheng Road Shanghai 201203 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sen","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengfei","family":"Shi","sequence":"additional","affiliation":[{"name":"The Soft2D Lab, State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"School of Electronic Information and Electrical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Senhe","family":"Huang","sequence":"additional","affiliation":[{"name":"The Soft2D Lab, State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengcheng","family":"Cai","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhui","family":"Zhu","sequence":"additional","affiliation":[{"name":"The Soft2D Lab, State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaodong","family":"Zhuang","sequence":"additional","affiliation":[{"name":"The Soft2D Lab, State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"Frontiers Science Center for Transformative Molecules Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  429 Zhangheng Road Shanghai 201203 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0026-5458","authenticated-orcid":false,"given":"Tianfu","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg6582"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01179-4"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","first-page":"1","author":"Zhan C.","year":"2024","journal-title":"Nat. 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