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Nevertheless, Zn anode encounters severe challenges, such as Zn dendrite formation, surface corrosion, and hydrogen evolution reaction (HER). Here, we report a strategy to spontaneously construct a boron\u2212fluoride dual\u2010atom regulated SEI (ZnBOF), which involves the formation of a B\u2010compound coating through an etching process followed by an in situ F substitution during the initial electrochemical cycling. The ZnBOF\/Zn anode benefits preferential deposition of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    along the (002) plane without Zn dendrite, and the side reactions including by\u2010product and HER are dramatically suppressed. A combination of characterization methods, such as X\u2010ray absorption spectroscopy, shows that the B\u2010containing passivation layer facilitates the transport of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    and mitigates water\u2010related side reactions, and the F atoms serve as zincophilic sites that enhance the transfer kinetics of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    . As expected, the well\u2010designed ZnBOF\/Zn anode exhibits ultra\u2010stable Zn plating\/stripping for 5000\u00a0h at 2\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The assembled ZnBOF\/Zn||MnO\n                    <jats:sub>2<\/jats:sub>\n                    batteries show impressive cycling stability, remaining 96.2% of the initial capacity (234.3\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) after 1700 cycles at 1.0\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Therefore, this work reveals a dual\u2010atom synergistic regulated strategy to fabricate a robust SEI for Zn anode, which contributes to the development of aqueous zinc\u2010based batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.202503376","type":"journal-article","created":{"date-parts":[[2025,3,22]],"date-time":"2025-03-22T08:51:10Z","timestamp":1742633470000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Boron\u2010Fluoride Dual\u2010atom Synergistic Regulated Interface Coating Enables Stable Zn\u2010Metal Anodes"],"prefix":"10.1002","volume":"64","author":[{"given":"Chenglong","family":"Liu","sequence":"first","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei Anhui 230029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruiqi","family":"Liu","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei Anhui 230029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuying","family":"Liu","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei Anhui 230029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Ma","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei Anhui 230029 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