{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T23:59:33Z","timestamp":1790812773214,"version":"4.1.0"},"reference-count":61,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T00:00:00Z","timestamp":1747612800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["INST 40\/575\u20101 FUGG"],"award-info":[{"award-number":["INST 40\/575\u20101 FUGG"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The coordination and functionalization of white phosphorus (P\n                    <jats:sub>4<\/jats:sub>\n                    ) by transition metal and main group element compounds have led to a great variety of polyphosphides. However, larger polyphosphides of the rare\u2010earth elements are elusive. In this study, we report the synthesis and full characterization of the largest polyphosphides of the f\u2010elements, [K(18\u2010crown\u20106)]\n                    <jats:sub>2<\/jats:sub>\n                    [(Cp\u2032\u2032\n                    <jats:sub>2<\/jats:sub>\n                    Ln)\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    <jats:sub>4<\/jats:sub>\n                    \u2010\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    :\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    :\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    :\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    P\n                    <jats:sub>14<\/jats:sub>\n                    )], which was isolated along with [K(18\u2010crown\u20106)][(Cp\u2032\u2032\n                    <jats:sub>2<\/jats:sub>\n                    Ln)\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    :\n                    <jats:italic>\u019e<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    P\n                    <jats:sub>3<\/jats:sub>\n                    )] (Ln\u00a0=\u00a0La, Ce, Cp\u2032\u2032\u00a0=\u00a01,3\u2010bis(trimethylsilyl)cyclopentadienyl). These compounds were obtained by using nonclassical divalent compounds of the early lanthanides for the reduction of white phosphorus.\n                  <\/jats:p>","DOI":"10.1002\/anie.202503403","type":"journal-article","created":{"date-parts":[[2025,4,29]],"date-time":"2025-04-29T11:59:43Z","timestamp":1745927983000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis of Molecular Organo\u2010f\u2010Element\u2010Polyphosphides with Nonclassical Divalent Lanthanide Precursors"],"prefix":"10.1002","volume":"64","author":[{"given":"David","family":"Frick","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstr. 12 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elena","family":"Pross","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstr. 12 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ralf","family":"K\u00f6ppe","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstr. 12 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstr. 12 76131 Karlsruhe Germany"},{"name":"Institute of Nanotechnology (INT) Karlsruhe Institute of Technology (KIT)  Kaiserstr. 12 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,19]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.133841"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197306941"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001630"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198408171"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19865390810"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT03174F"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500387w"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460427"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adomc.2019.06.001"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001854"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351776"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500414"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00657-7"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae162"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06730G"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201300225"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100605"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC01519H"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17638f"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b00589"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60163C"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC05056D"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201900181"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc38841g"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00429"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b13081"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja901045m"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC02252E"},{"key":"e_1_2_6_30_1","first-page":"59","volume":"26","author":"Scherer O. 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