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It is essential to elucidate the reasons and propose effective strategies. Here, the capacity\u2010fading mechanism of commercial NaFe\n                    <jats:sub>1\/3<\/jats:sub>\n                    Mn\n                    <jats:sub>1\/3<\/jats:sub>\n                    Ni\n                    <jats:sub>1\/3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    is due to the dissolution of iron ions. Additionally, the extraction of sodium ions (after the Fe\n                    <jats:sup>3+<\/jats:sup>\n                    \/Fe\n                    <jats:sup>4+<\/jats:sup>\n                    reaction) lowers the energy level of NaFe\u2081\/\u2083Mn\u2081\/\u2083Ni\u2081\/\u2083O\u2082 below that of the electrolyte solvent, thereby inducing solvent decomposition. We establish screening criteria for electrolyte additives through theoretical calculations to improve capacity retention. We identified a series of nitrogen\u2010containing Lewis base additives that can kinetically bind efficiently to iron ions in NaFe\u2081\/\u2083Mn\u2081\/\u2083Ni\u2081\/\u2083O\u2082 and thermodynamically exhibit stronger electron\u2010donating abilities than the solvents. A new compound, sodium bis(trimethylsilyl)amide (which has not been studied as a Na\u2010ion battery additive before), is selected through the Reaxys database (out of 61 molecules) because it is commercially available at a low price and is relatively stable in the electrochemical process. Such an additive is demonstrated to greatly improve the Coulombic efficiency and reduce the dissolution of iron ions of NaFe\u2081\/\u2083Mn\u2081\/\u2083Ni\u2081\/\u2083O\u2082\/\/hard carbon cells.\n                  <\/jats:p>","DOI":"10.1002\/anie.202503587","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T00:38:16Z","timestamp":1742863096000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Strategy Formulation for Mitigating Capacity Fading of Na\u2010Layered Oxides"],"prefix":"10.1002","volume":"64","author":[{"given":"Jun","family":"Pan","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering Nanyang Technological University  Singapore 639798 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Radiology Shandong First Medical 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